937029

rac-BINAP Pd G4 ChemBeads

• 别名: (Methanesulfonatato-κO)[2′-(methylamino-κN)-2-biphenylyl-κC2]palladium - 1,1′-binaphthalene-2,2′-diylbis(diphenylphosphine)
• 经验公式（希尔记法）: C₅₈H₄₇NO₃P₂PdS
• CAS号: 1599466-90-6
• 分子量: 1006.43
• 分類程式碼代碼: 31191513
• NACRES: NA.21

属性

• 形狀: solid
• 品質等級: 100
• 成份: loading of catalyst, ~5 wt. %
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• SMILES 字串: O=S(=O)([O-][Pd+2]1([C-]=2C=CC=CC2C=3C=CC=CC3[NH]1C)[P](C=4C=CC=CC4)(C=5C=CC=CC5)C=6C=CC=7C=CC=CC7C6C8=C9C=CC=CC9=CC=C8P(C=%10C=CC=CC%10)C=%11C=CC=CC%11)C
• InChI: InChI:1S/C44H32P2.C13H12N.CH4O3S.Pd/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;1-14-13-10-6-5-9-12(13)11-7-3-2-4-8-11;1-5(2,3)4;/h1-32H;2-7,9-10,14H,1H3;1H3,(H,2,3,4);/q;;;+1/p-1
• InChI 密鑰: JCAKNOAUMBTXEM-UHFFFAOYSA-M

说明

一般說明

rac-BINAP Pd G4 powerful ligand for classic cross-coupling reactions combined with the Buchwald Fourth Generation Palladacycle. Bench stable, soluble in most organic solvents.

應用

ChemBeads are chemical coated glass beads. ChemBeads offer improved flowability and chemical uniformity perfect for automated solid dispensing and high-throughput experimentation. The method of creating ChemBeads uses no other chemicals or surfactants allowing the user to accurately dispense sub-milligram amounts of chemical.

For larger scale uses, product also available in powdered form (900340)

其他說明

High-Throughput Reaction Screening with Nanomoles of Solid Reagents Coated on Glass Beads

Versatile Methods to Dispense Sub-Milligram Quantities of Solids using Chemical Coated Beads for High-Throughput Experimentation

ChemBead Enabled High-Throughput Cross-Electrophile Coupling Reveals a New Complementary Ligand

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3