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Merck

90383

Supelco

三乙基氯硅烷

for GC derivatization, LiChropur, ≥97.0% (GC)

别名:

TESCl, Triethylchlorosilane

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About This Item

线性分子式:
(C2H5)3SiCl
CAS号:
分子量:
150.72
Beilstein:
1732860
EC號碼:
MDL號碼:
分類程式碼代碼:
12000000
PubChem物質ID:
NACRES:
NA.22

等級

for GC derivatization

品質等級

化驗

≥97.0% (GC)

形狀

liquid

品質

LiChropur

反應適用性

reagent type: derivatization reagent
reaction type: Silylations

技術

gas chromatography (GC): suitable

折射率

n20/D 1.43 (lit.)

bp

142-144 °C (lit.)

密度

0.898 g/mL at 25 °C (lit.)

SMILES 字串

CC[Si](Cl)(CC)CC

InChI

1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3

InChI 密鑰

DCFKHNIGBAHNSS-UHFFFAOYSA-N

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一般說明

Chlorotriethylsilane may be used as a silylating reagent for the preparation of trisilyl ethers from alcohols in the presence of a base such as imidazole, pyridine or 4-(dimethylamino)pyridine. It is found to be more reactive when used with pyridine as a solvent.

應用

Chlorotriethylsilane may be used as a derivatizing reagent for the determination of fluoride, in toothpaste samples using headspace solid-phase microextraction and gas chromatography–flame ionization detection.

其他說明

本品是一种硅烷化试剂,在某些合成或者分析应用方面优于三甲基硅烷化试剂

法律資訊

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

86.0 °F

閃點(°C)

30 °C

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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分析证书(COA)

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访问文档库

W.C. Still et al.
Journal of the American Chemical Society, 99, 948-948 (1977)
Determination of fluoride in toothpaste using headspace solid-phase microextraction and gas chromatography?flame ionization detection
Wejnerowska G, et al.
Journal of Chromatography A, 1150(1-2), 173-177 (2007)
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 4 (2014)
J. Heberle et al.
Silylating Agents, 2nd ed. (1995)
C.F. Poole et al.
Journal of Chromatographic Science, 17, 115-115 (1979)

商品

Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs

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