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等級
for GC derivatization
品質等級
化驗
≥97.0% (GC)
形狀
liquid
品質
LiChropur™
反應適用性
reagent type: derivatization reagent
reaction type: Silylations
技術
gas chromatography (GC): suitable
折射率
n20/D 1.43 (lit.)
bp
142-144 °C (lit.)
密度
0.898 g/mL at 25 °C (lit.)
SMILES 字串
CC[Si](Cl)(CC)CC
InChI
1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3
InChI 密鑰
DCFKHNIGBAHNSS-UHFFFAOYSA-N
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一般說明
Chlorotriethylsilane may be used as a silylating reagent for the preparation of trisilyl ethers from alcohols in the presence of a base such as imidazole, pyridine or 4-(dimethylamino)pyridine. It is found to be more reactive when used with pyridine as a solvent.
應用
Chlorotriethylsilane may be used as a derivatizing reagent for the determination of fluoride, in toothpaste samples using headspace solid-phase microextraction and gas chromatography–flame ionization detection.
其他說明
本品是一种硅烷化试剂,在某些合成或者分析应用方面优于三甲基硅烷化试剂
法律資訊
LiChropur is a trademark of Merck KGaA, Darmstadt, Germany
訊號詞
Danger
危險分類
Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 1
閃點(°F)
86.0 °F
閃點(°C)
30 °C
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Journal of the American Chemical Society, 99, 948-948 (1977)
Determination of fluoride in toothpaste using headspace solid-phase microextraction and gas chromatography?flame ionization detection
Journal of Chromatography A, 1150(1-2), 173-177 (2007)
Science of Synthesis: Houben-Weyl Methods of Molecular Transformations, 4 (2014)
Silylating Agents, 2nd ed. (1995)
Journal of Chromatographic Science, 17, 115-115 (1979)
商品
Results of a study involving the ability few Fluka silylating reagents to form GC-MS-compatible trimethylsilylmethyl derivatives of NSAIDs
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