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76886

Sigma-Aldrich

三(4,7-联苯-1,10-菲咯啉)二氯化钌(II)复合物

for fluorescence

别名:

Ru(ddp)

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About This Item

经验公式（希尔记法）:
C72H48Cl2N6Ru
CAS号:
36309-88-3
分子量:
1169.17
MDL编号:
MFCD03095387
UNSPSC代码:
12352103
PubChem化学物质编号:
329767411

等级

for fluorescence

方案

≥95% (HPCE)

表单

powder

溶解性

DMF: soluble
chloroform: soluble
ethanol: soluble
methanol: soluble

荧光

λex 455 nm; λem 610-630 nm in 0.1 M phosphate pH 7.0

适用性

suitable for fluorescence

SMILES字符串

Cl[Ru]Cl.c1ccc(cc1)-c2ccnc3c2ccc4c(ccnc34)-c5ccccc5.c6ccc(cc6)-c7ccnc8c7ccc9c(ccnc89)-c%10ccccc%10.c%11ccc(cc%11)-c%12ccnc%13c%12ccc%14c(ccnc%13%14)-c%15ccccc%15

InChI

1S/3C24H16N2.2ClH.Ru/c3*1-3-7-17(8-4-1)19-13-15-25-23-21(19)11-12-22-20(14-16-26-24(22)23)18-9-5-2-6-10-18;;;/h3*1-16H;2*1H;/q;;;;;+2/p-2

InChI key

SKZWFYFFTOHWQP-UHFFFAOYSA-L

应用

三(4,7-联苯-1,10-菲咯啉)二氯化钌 (Ru(dpp)) 和三(4,7-联苯-1,10-菲咯啉)钌六氟磷酸盐 (Ru(dpp)3(PF6)2) 广泛用作发光检测和氧气定量测定的探针。
两种染料的荧光（吸光λmax 455nm，发光 λmax 613nm）因动态猝灭而被分子氧显著减弱。因此，它是基于强度或衰减时间测量的有效氧探针。
三(4,7-联苯-1,10-菲咯啉)二氯化钌已用于（纤维）光传感器、皮肤和皮肤瘤中氧的研究、皮肤中氧通量的测量以及氧成像。

包装

Bottomless glass bottle. Contents are inside inserted fused cone.

储存分类代码

13 - Non Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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W L Rumsey et al.
Science (New York, N.Y.), 241(4873), 1649-1651 (1988-09-23)
The imaging of phosphorescence provides a method for monitoring oxygen distribution within the vascular system of intact tissues. Isolated rat lives were perfused through the portal vein with media containing palladium coproporphyrin, which phosphoresced and was used to image the
G. Liebsch et al.
Appl. Spectroscopy, 54, 548-548 (2000)
Federica Tonon et al.
Scientific reports, 9(1), 13557-13557 (2019-09-21)
Among the multiple metabolic signals involved in the establishment of the hepatic zonation, oxygen could play a key role. Indeed, depending on hepatocyte position in the hepatic lobule, gene expression and metabolism are differently affected by the oxygen gradient present
Yuta Ando et al.
Advanced healthcare materials, 8(5), e1900001-e1900001 (2019-02-09)
Despite its revolutionary success in hematological malignancies, chimeric antigen receptor T (CAR-T) cell therapy faces disappointing clinical results in solid tumors. The poor efficacy has been partially attributed to the lack of understanding in how CAR-T cells function in a
Yuta Ando et al.
Scientific reports, 7(1), 15233-15233 (2017-11-11)
Hypoxia plays a central role in cancer progression and resistance to therapy. We have engineered a microdevice platform to recapitulate the intratumor oxygen gradients that drive the heterogeneous hypoxic landscapes in solid tumors. Our design features a "tumor section"-like culture
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