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Merck

309443

Sigma-Aldrich

(±)-1,3-丁二醇

anhydrous, ≥99%

别名:

1,3-丁二醇

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About This Item

线性分子式:
CH3CH(OH)CH2CH2OH
CAS号:
分子量:
90.12
Beilstein:
1731276
EC號碼:
MDL號碼:
分類程式碼代碼:
12352001
PubChem物質ID:
NACRES:
NA.21

等級

anhydrous

品質等級

蒸汽密度

3.1 (20 °C, vs air)

蒸汽壓力

0.06 mmHg ( 20 °C)

化驗

≥99%

形狀

liquid

自燃溫度

741 °F

expl. lim.

0.34-6.3 %

雜質

<0.003% water
<0.005% water (100 mL pkg)

折射率

n20/D 1.44 (lit.)

pH值

6.0-7.0 (20 °C)

bp

203-204 °C (lit.)

mp

-54 °C

密度

1.005 g/mL at 25 °C (lit.)

SMILES 字串

CC(O)CCO

InChI

1S/C4H10O2/c1-4(6)2-3-5/h4-6H,2-3H2,1H3

InChI 密鑰

PUPZLCDOIYMWBV-UHFFFAOYSA-N

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應用

在通过 2-羟基-4-甲氧基苯基氯化铵与尿素的缩合反应制备 6-甲氧基-2-苯并恶唑啉酮中,(±)-1,3-丁二醇可作为溶剂。也可在三甲基氯硅烷存在下与羧酸反应生成相应的的氯醇酯。

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 1

閃點(°F)

226.4 °F - closed cup

閃點(°C)

108 °C - closed cup

個人防護裝備

Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)


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6-methoxy-2-benzoxazolinone synthesis in 1,3-butanediol.
Richey JD, et al.
Agricultural and Biological Chemistry, 40(12), 2413-2416 (1976)
Access to (S)-2-methyloxetane and the precursor (S)-1, 3-butanediol of high enantiomeric purity.
Hintzer K, et al.
The Journal of Organic Chemistry, 47(20), 3850-3854 (1982)
Influence of Carboxylic Acids on the Synthesis of Chlorohydrin Esters from 1, 3?Butanediol
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Synthetic Communications, 36(9), 1167-1175 (2006)
Optical resolution by vapour permeation of 1, 3-butanediol and 2-butanol through (+)-poly1-[dimethyl (10-pinanyl) silyl]-1-propyne membrane.
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