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Merck

243434

Sigma-Aldrich

granular, 0.425-2.0 mm particle size, ≥99.5%, ACS reagent

别名:

Sn

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About This Item

经验公式(希尔记法):
Sn
CAS号:
分子量:
118.71
EC號碼:
MDL號碼:
分類程式碼代碼:
12161600
PubChem物質ID:
NACRES:
NA.22

等級

ACS reagent

品質等級

化驗

≥99.5%

形狀

granular

反應適用性

core: tin
reagent type: catalyst

電阻係數

11 μΩ-cm, 20°C

粒徑

0.425-2.0 mm

bp

2270 °C (lit.)

mp

231.9 °C (lit.)

密度

7.310 g/mL at 25 °C (lit.)

正離子痕跡

As: ≤1 ppm
Cu: ≤0.005%
Fe: ≤0.01%
Pb: ≤0.005%
Sb: ≤0.02%

SMILES 字串

[Sn]

InChI

1S/Sn

InChI 密鑰

ATJFFYVFTNAWJD-UHFFFAOYSA-N

相关类别

一般說明

Tin (Sn) is a silvery-white metal that is malleable and ductile at ordinary temperatures. It is used as a catalyst in organic synthesis. It is also used in various sectors, such as nuclear energy, plastics, polymers, agriculture, biochemistry, and in glassmaking.

應用

用于津特尔相 SrSn3Sb4 的固态合成,它具有一个 30 元环的阴离子通道骨架。
Tin can be used in the following:      
  • With HCl, it reduces a variety of functional groups.
  • Stereoselective allylation of carbonyl compounds.     
  • In situ generations of tin enolates for directed aldol reactions.
  • Preparation of organotin reagents.

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Donna T. Chow et al.
Inorganic chemistry, 36(17), 3750-3753 (1997-08-13)
The new Zintl compound strontium tin antimonide, SrSn(3)Sb(4), has been synthesized, and its structure has been determined by single-crystal X-ray diffraction methods. It crystallizes in the orthorhombic space group -Pnma with a = 10.060(2) Å, b = 4.361(1) Å, c
D B Shpakovsky et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14568-14582 (2012-10-12)
Four new organotin(IV) complexes of bis-(2,6-di-tert-butylphenol)tin(IV) dichloride [(tert-Bu-)(2)(HO-Ph)](2)SnCl(2) (1) with the heterocyclic thioamides 2-mercapto-pyrimidine (PMTH), 2-mercapto-4-methyl-pyrimidine (MPMTH), 2-mercapto-pyridine (PYTH) and 2-mercapto-benzothiazole (MBZTH), of formulae {[(tert-Bu-)(2)(HO-Ph)](2)Sn(PMT)(2)} (2), {[(tert-Bu-)(2)(HO-Ph)](2)Sn(MPMT)(2)} (3), {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(PYT)} (4) and {[(tert-Bu-)(2)(HO-Ph)](2)SnCl(MBZT)} (5), have been synthesized and characterized by elemental
P Olmedo et al.
Environment international, 59, 63-72 (2013-06-25)
Although fish intake has potential health benefits, the presence of metal contamination in seafood has raised public health concerns. In this study, levels of mercury, cadmium, lead, tin and arsenic have been determined in fresh, canned and frozen fish and
A Gassenq et al.
Optics express, 20(25), 27297-27303 (2012-12-25)
A surface-illuminated photoconductive detector based on Ge0.91Sn0.09 quantum wells with Ge barriers grown on a silicon substrate is demonstrated. Photodetection up to 2.2µm is achieved with a responsivity of 0.1 A/W for 5V bias. The spectral absorption characteristics are analyzed
Shiyou Chen et al.
Advanced materials (Deerfield Beach, Fla.), 25(11), 1522-1539 (2013-02-13)
The kesterite-structured semiconductors Cu2ZnSnS4 and Cu2ZnSnSe4 are drawing considerable attention recently as the active layers in earth-abundant low-cost thin-film solar cells. The additional number of elements in these quaternary compounds, relative to binary and ternary semiconductors, results in increased flexibility

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