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Merck

M29304

Sigma-Aldrich

N-甲基苯胺

98%

别名:

一甲基苯胺

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About This Item

线性分子式:
C6H5NHCH3
CAS号:
分子量:
107.15
Beilstein:
741982
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.571 (lit.)

bp

196 °C (lit.)

mp

−57 °C (lit.)

密度

0.989 g/mL at 25 °C (lit.)

SMILES 字串

CNc1ccccc1

InChI

1S/C7H9N/c1-8-7-5-3-2-4-6-7/h2-6,8H,1H3

InChI 密鑰

AFBPFSWMIHJQDM-UHFFFAOYSA-N

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應用

N-甲基苯胺是用于以下方面的通用试剂:
  • 针对铑催化不对称硼氢化制备亚磷酰胺配体。
  • 作为C3选择性吲哚甲酰化的甲酰化试剂。
  • 合成了一种基于红质的荧光探针,HKGreen-3,用于检测过亚硝酸根。
  • 作为合成AKT(蛋白激酶B)抑制剂-IV的关键起始物料。

訊號詞

Danger

危險分類

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Irrit. 2 - STOT RE 2 Oral

標靶器官

Liver,spleen,Bone marrow

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 3

閃點(°F)

185.0 °F - closed cup

閃點(°C)

85 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Efficient amide-directed catalytic asymmetric hydroboration.
Smith S M, et al.
Journal of the American Chemical Society, 130(12), 3734-3735 (2008)
Synthesis and biological evaluation of analogues of AKT (protein kinase B) inhibitor-IV.
Sun Q, et al.
Journal of Medicinal Chemistry, 54(5), 1126-1139 (2011)
HKGreen-3: a rhodol-based fluorescent probe for peroxynitrite.
Peng T and Yang D
Organic Letters, 12(21), 4932-4935 (2010)
S Ramalingam et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 76(1), 84-92 (2010-03-26)
The FTIR and FTRaman spectra of 2-bromo-4-methyl aniline (2-B-4-MA) molecule have been recorded using Brucker IFS 66V spectrometer in the range of 4000-100 cm(-1). The molecular geometry and vibrational frequencies in the ground state are calculated using the Hartree-Fock (HF)
Jonathan L Sessler et al.
Chemical communications (Cambridge, England), (14)(14), 1892-1894 (2005-03-30)
A novel porphyrin-fullerene dyad assembled through Watson-Crick hydrogen bonds is described; this system undergoes photoinduced electron transfer upon irradiation with visible light to produce a charge separated state that is substantially longer lived than that of previous dyads of this

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