化驗
≥99.9%
形狀
wire
製造商／商標名
Goodfellow 999-455-34
電阻係數
4.71 μΩ-cm
bp
4130 °C (lit.)
mp
2450 °C (lit.)
密度
22.65 g/cm3 (lit.)
SMILES 字串
[Ir]
InChI
1S/Ir
InChI 密鑰
GKOZUEZYRPOHIO-UHFFFAOYSA-N
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一般說明
For updated SDS information please visit www.goodfellow.com.
法律資訊
Product of Goodfellow
Veronica Marin et al.
Chemical Society reviews, 36(4), 618-635 (2007-03-28)
The need for novel materials with luminescent properties and advanced processing features requires reliable and reproducible synthetic routes for the design of suitable materials, such as e.g. polypyridyl ruthenium(II) and iridium(III)-containing polymers. The most popular ligand for those purposes is
Etienne Baranoff et al.
Chemical Society reviews, 33(3), 147-155 (2004-03-18)
In order to mimic the photosynthetic reaction centre and better understand photoinduced electron transfer processes, a family of compounds has been studied for the past 15 years. These are transition metal complexes, M(tpy)(2) where tpy is a 2,2':6',2" terpyridine based
Low-valent ruthenium and iridium hydride complexes as alternatives to Lewis acid and base catalysts.
S Murahashi et al.
Accounts of chemical research, 33(4), 225-233 (2000-04-25)
The discovery of a new chemical reaction often leads to new applications and new chemical principles. Low-valent ruthenium and iridium hydride complexes are highly useful redox Lewis acid and base catalysts. Nitriles are activated by these catalysts and undergo reactions
Soo Bong Han et al.
Chemical communications (Cambridge, England), (47)(47), 7278-7287 (2009-12-22)
Existing methods for enantioselective carbonyl allylation, crotylation and tert-prenylation require stoichiometric generation of pre-metallated nucleophiles, and often employ stoichiometric chiral modifiers. Under the conditions of transfer hydrogenation employing an ortho-cyclometallated iridium C,O-benzoate catalyst, enantioselective carbonyl allylations, crotylations and tert-prenylations are
Paolo Tosatti et al.
Organic & biomolecular chemistry, 10(16), 3147-3163 (2012-03-13)
Since their discovery in 1997, iridium-catalysed asymmetric allylic substitutions have been developed into a broadly applicable tool for the synthesis of chiral building blocks via C-C and C-heteroatom bond formation. The remarkable generality of these reactions and the high levels
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