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Merck
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文件

D12600

Sigma-Aldrich

3,4-二氨基苯甲酸

97%

别名:

4-Carboxy-o-phenylenediamine

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About This Item

线性分子式:
(H2N)2C6H3CO2H
CAS号:
619-05-6
分子量:
152.15
Beilstein:
775892
EC號碼:
210-577-2
MDL號碼:
MFCD00007726
分類程式碼代碼:
12352200
PubChem物質ID:
24893391
NACRES:
NA.22

化驗

97%

形狀

powder

反應適用性

reaction type: solution phase peptide synthesis

mp

208-210 °C (dec.) (lit.)

應用

peptide synthesis

SMILES 字串

Nc1ccc(cc1N)C(O)=O

InChI

1S/C7H8N2O2/c8-5-2-1-4(7(10)11)3-6(5)9/h1-3H,8-9H2,(H,10,11)

InChI 密鑰

HEMGYNNCNNODNX-UHFFFAOYSA-N

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應用

3,4-二氨基苯甲酸可用于制备：
  • 席夫碱衍生物（通过与取代醛及其相应的金属络合物反应生成）
  • 聚（2，5-苯并咪唑）(ABPBI) 聚合物（通过与甲磺酸和P2O5反应生成）
  • 适用于H2O裂解反应的Pt基席夫碱络合物。

3,4-二氨基苯甲酸通过环缩合反应形成，如喹喔啉和 苯并咪唑。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 1

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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N Sundaraganesan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 70(2), 376-383 (2007-12-28)
The Fourier Transform Raman and Fourier Transform infrared spectra of 3,4-diaminobenzoic acid (3,4-DABA) were recorded in the solid phase. Geometry optimizations were done without any constraint and harmonic-vibrational wave numbers and several thermodynamic parameters were calculated for the minimum energy
New platinum and ruthenium Schiff base complexes for water splitting reactions
Wang C, et al.
Dalton Transactions, 44(32), 14483-14493 (2015)
New 3, 4-diaminobenzoic acid Schiff base compounds and their complexes: Synthesis, characterization and thermodynamics
Mohammadi K, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 122, 179-185 (2014)
L A Cooper et al.
Antonie van Leeuwenhoek, 50(1), 53-62 (1984-01-01)
The effect of various compounds on growth, melanin biosynthesis and cell differentiation was studied in a hyaline (SH25) and a pigmented (SH25B) strain of Microdochium bolleyi. Dark pigment production by the hyaline strain was induced by the presence of DOPA
S Ram et al.
Journal of medicinal chemistry, 35(3), 539-547 (1992-02-07)
A series of methyl and ethyl 5-(alkoxycarbonyl)-1H-benzimidazole-2-carbamates (7-19) and methyl 5-carbamoyl-1H-benzimidazole-2-carbamates (24-34) have been synthesized via the reaction of an appropriate alcohol or amine with the acid chloride derivatives 6a or 6b at room temperature. Reaction of an alcohol with
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