跳转至内容
Merck
所有图片(1)

文件

ALD00632

Sigma-Aldrich

Methyl (-)-PI Reagent

≥95%

别名:

1,3,2-Benzoxathiaphosphole, hexahydro-2,7a-dimethyl-5-(1-methylethenyl)-, 2-sulfide, (2S,3aS,5R,7aS)

登录查看公司和协议定价
所有图片(1)

About This Item

经验公式（希尔记法）:
C11H19OPS2
CAS号:
2408772-79-0
分子量:
262.37
分類程式碼代碼:
12352005
NACRES:
NA.06

品質等級

100

化驗

≥95%

形狀

powder

儲存溫度

2-8°C

SMILES 字串

[H][C@@]1(S[P@](O2)(C)=S)[C@]2(C)CC[C@@H](C(C)=C)C1

應用

Methyl (-)-PI Reagent is a methyl substituted analog of the air and moisture-tolerant (-)-PI reagent developed in the Baran lab for stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides.

Learn more about PI and PSI reagents

其他說明

Enantiodivergent formation of C-P bonds: synthesis of P-chiral phosphines and methyl-phosphonate oligonucleotides

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Dongmin Xu et al.
Journal of the American Chemical Society, 142(12), 5785-5792 (2020-02-29)
Phosphorus Incorporation (PI, abbreviated Π) reagents for the modular, scalable, and stereospecific synthesis of chiral phosphines and methylphosphonate nucleotides are reported. Synthesized from trans-limonene oxide, this reagent class displays an unexpected reactivity profile and enables access to chemical space distinct

商品

PI and PSI – Chiral phosphorus incorporation harnessing the potential of P(V)

PI and PSI reagents are a platform of phosphate-based reagents for phosphorylation and phosphothiolation of nucleotides and peptides developed by the Baran lab.

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门