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Merck

935611

Sigma-Aldrich

碳酸乙烯亚乙酯

new
greener alternative

≥99.9%, anhydrous, battery grade

别名:

4-乙烯基-1,3-二氧戊环-2-酮, VEC

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About This Item

经验公式(希尔记法):
C5H6O3
CAS号:
分子量:
114.10
MDL號碼:
分類程式碼代碼:
12352005

等級

battery grade

品質等級

描述

Application: Battery manufacturing

化驗

≥99.9%

形狀

liquid

環保替代產品特色

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

雜質

≤100 ppm H2O

折射率

n20/D 1.45 (lit.)

bp

237 °C/733 mmHg (lit.)

密度

1.188 g/mL at 25 °C (lit.)

應用

battery manufacturing

環保替代類別

儲存溫度

2-8°C

SMILES 字串

C=CC1COC(=O)O1

InChI

1S/C5H6O3/c1-2-4-3-7-5(6)8-4/h2,4H,1,3H2

InChI 密鑰

BJWMSGRKJIOCNR-UHFFFAOYSA-N

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一般說明

4-Vinyl-1,3-dioxolan-2-one (VEC) is a cyclic organic compound with the molecular formula C5H6O3. It is a clear, colorless liquid with a high boiling point and is miscible with carbonate and ether solvents used in lithium-ion batteries (LIBs). Our battery grade VEC is differentiated by its high purity and low trace moisture to help ensure consistent performance in battery applications.
We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Click here for more information.

應用

Anhydrous, battery grade 4-vinyl-1,3-dioxolan-2-one (VEC) is commonly used as an electrolyte additive in lithium-ion batteries (LIBs) to improve battery performance. VEC helps to form a stable film on the anode surface called a solid electrolyte interface (SEI). The SEI acts as a barrier that prevents further reaction between the electrolyte and the anode and thereby enhances the cyclic stability of the battery. For example, the addition of 2 wt.% VEC to the electrolyte formulation enhanced cycling performance in experiments both with Li metal anodes and graphite anodes In the electrolyte formulation, often VEC is added to be 2-10 wt.% of the solvent blend; however, scientists have even used VEC as the sole solvent in a lithium-metal battery with great results including long cycle life over 1000 cycles and reduced flammability

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产品编号
说明
价格

象形圖

Skull and crossbones

訊號詞

Danger

危險聲明

危險分類

Acute Tox. 3 Oral

儲存類別代碼

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

水污染物質分類(WGK)

WGK 1

閃點(°F)

206.4 °F - closed cup

閃點(°C)

96.9 °C - closed cup


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Vinyl ethylene carbonate as an electrolyte additive for high-voltage LiNi0.4Mn0.4Co0.2O2/graphite Li-ion batteries
Zuo X, et al.
Ionics, 22, 201-208 (2016)
Highly safe and cyclable Li-metal batteries with vinylethylene carbonate electrolyte
Zhang Q, et al.
Nano Energy, 74, 104860-104860 (2020)
Vinyl Ethylene Carbonate as an Effective SEI-Forming Additive in Carbonate-Based Electrolyte for Lithium-Metal Anodes
Yang Y, et al.
ACS Applied Materials & Interfaces, 11, 6118-6125 (2019)

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