923451

(PhMPhos)PdCl₂

complex with CH₂Cl₂

• 别名: 1-Diadamantylphosphino-1′-diphenylphosphinoferrocene palladium dichloride
• 经验公式（希尔记法）: C₄₂H₄₈Cl₂FeP₂Pd
• CAS号: 2768152-18-5
• 分子量: 847.95
• 分類程式碼代碼: 12352101
• NACRES: NA.21

属性

• 品質等級: 100
• 形狀: powder
• 反應適用性: reagent type: catalyst; reaction type: Cross Couplings

说明

應用

(PhMPhos)PdCl₂ is an unsymmetrical ferrocene-based Pd-catalyst. The MPhos series of ligands are unsymmetrical diphosphino-ferrocenes bearing a bulky adamantyl group. (PhMPhos)PdCl₂ can be used for a variety of cross-coupling transformations, including Suzuki coupling, C-P coupling, and Csp²-Csp³ coupling. Demonstrated Csp²-Csp³ couplings include Murahashi-Feringa Coupling (Alkyl-Li), Kumada-Corriu coupling (Alkyl-MgX), Negishi coupling (Alkyl-ZnX) and Suzuki–Miyaura coupling (Alkyl-B(OR₂)).

Learn more about MPhos ligands and catalysts

其他說明

Tunable Unsymmetrical Ferrocene Ligands Bearing a Bulky Di-1-adamantylphosphino Motif for Many Kinds of Csp²–Csp³ Couplings

安全信息

• 象形圖: GHS08,GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H351
• 防範說明: P202 - P264 - P280 - P302 + P352 - P305 + P351 + P338 - P308 + P313
• 危險分類: Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable