900715

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide

• 别名: Chiral MPAO ligand
• 经验公式（希尔记法）: C₂₃H₂₈N₂O₂
• CAS号: 2079094-32-7
• 分子量: 364.48
• UNSPSC代码: 12161600
• NACRES: NA.22

属性

• 方案: ≥95%
• 表单: powder or crystals
• 反应适用性: reaction type: C-C Bond Formation; reagent type: catalyst; reagent type: ligand; reaction type: C-H Activation
• mp: 130 °C
• 官能团: amide; phenyl
• 储存温度: 2-8°C

说明

应用

N-((S)-1-((4S,5S)-4-Benzyl-5-phenyl-4,5-dihydrooxazol-2-yl)-2,2-dimethylpropyl)acetamide is a chiral ligand developed by Jin-Quan Yu′s lab for Pd(II)-catalyzed enantioselective β-C(sp³)H arylation, alkenylation, and alkynylation. This mono-protected aminomethyl oxazoline (MPAO) ligand was used in the challenging desymmetrization of isopropyl groups.

其他说明

Formation of α-chiral centers by asymmetric β-C(sp³)–H arylation, alkenylation, and alkynylation

安全信息

• 危险声明: H413
• 危险分类: Aquatic Chronic 4
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable