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Merck
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文件

805807

Sigma-Aldrich

FK 269 Co (III) TFSI 盐

别名:

Greatcell Solar®, bis(2,6-di(1H-pyrazol-1-yl)pyridine)cobalt(III) tri[bis(trifluoromethane)sulfonimide]

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About This Item

经验公式（希尔记法）:
C28H18CoF18N13O12S6
分子量:
1321.82
分類程式碼代碼:
12352103
PubChem物質ID:
329768961
NACRES:
NA.23

化驗

98%

形狀

powder

mp

169.5 °C

SMILES 字串

O=S([N-]S(=O)(C(F)(F)F)=O)(C(F)(F)F)=O.C1(N2N=CC=C2)=CC=CC(N3C=CC=N3)=N1.N4(C5=NC(N6N=CC=C6)=CC=C5)N=CC=C4.[Co+3]

InChI

1S/2C11H9N5.C2F6NO4S2.Co/c2*1-4-10(15-8-2-6-12-15)14-11(5-1)16-9-3-7-13-16;3-1(4,5)14(10,11)9-15(12,13)2(6,7)8;/h2*1-9H;;/q;;-1;+3

InChI 密鑰

ZURJMCGADUHLSF-UHFFFAOYSA-N

應用

Use this cobalt complexes to increase photovoltages of liquid electrolyte cells substantially or to achieve ultrahigh performance with solid state photovoltaic devices, such as perovskite and dye-sensitized solar cells
FK269 cobalt complexes offer guaranteed performance, high reproducibility, consistent results, and are of highest purity. In comparison to triiodide-based redox electrolytes, cobalt complexes in general increase photovoltages and, particularly at lower light levels (e.g. for indoor applications), significantly increase device power output.

法律資訊

Product of Greatcell Solar®
Greatcell Solar is a registered trademark of Greatcell Solar

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

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Teck Ming Koh et al.
ChemSusChem, 7(7), 1909-1914 (2014-05-23)
In this work, we report a new cobalt(III) complex, tris[2-(1H-pyrazol-1-yl)pyrimidine]cobalt(III) tris[bis(trifluoromethylsulfonyl)imide] (MY11), with deep redox potential (1.27 V vs NHE) as dopant for 2,2',7,7'-tetrakis-(N,N-di-p-methoxyphenylamine)-9,9'-spirobifluorene (spiro-OMeTAD). This dopant possesses, to the best of our knowledge, the deepest redox potential among all
Sandra M Feldt et al.
Physical chemistry chemical physics : PCCP, 15(19), 7087-7097 (2013-04-05)
Regeneration and recombination kinetics was investigated for dye-sensitized solar cells (DSCs) using a series of different cobalt polypyridine redox couples, with redox potentials ranging between 0.34 and 1.20 V vs. NHE. Marcus theory was applied to explain the rate of
Julian Burschka et al.
Nature, 499(7458), 316-319 (2013-07-12)
Following pioneering work, solution-processable organic-inorganic hybrid perovskites-such as CH3NH3PbX3 (X = Cl, Br, I)-have attracted attention as light-harvesting materials for mesoscopic solar cells. So far, the perovskite pigment has been deposited in a single step onto mesoporous metal oxide films
Edoardo Mosconi et al.
Journal of the American Chemical Society, 134(47), 19438-19453 (2012-11-02)
We report a combined experimental and computational investigation to understand the nature of the interactions between cobalt redox mediators and TiO(2) surfaces sensitized by ruthenium and organic dyes, and their impact on the performance of the corresponding dye-sensitized solar cells

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