804584

(S,R)-Bode Kinetic Resolution Catalyst

• 别名: (4aS,9aR)-6-Bromo-4-hydroxy-4,4a,9,9a-tetrahydroindeno[2,1-b][1,4]oxazin-3(2H)-one
• 经验公式（希尔记法）: C₁₁H₁₀BrNO₃
• CAS号: 1417826-81-3
• 分子量: 284.11
• 分類程式碼代碼: 12352101
• PubChem物質ID: 329768884
• NACRES: NA.22

属性

• 形狀: solution
• 官能基: bromo; ether
• 儲存溫度: 15-25°C
• SMILES 字串: O=C(CO1)N(O)[C@]2([H])[C@@]1([H])CC3=CC=C(Br)C=C32
• InChI: 1S/C11H10BrNO3/c12-7-2-1-6-3-9-11(8(6)4-7)13(15)10(14)5-16-9/h1-2,4,9,11,15H,3,5H2/t9-,11+/m1/s1
• InChI 密鑰: FQXSUQCCAHKURK-KOLCDFICSA-N

说明

應用

The following organocatalyst is used in the kinetic resolution of cyclic amines as reported by Bode and coworkers. In tandem with acylating reagent, (1E)-4-Hydroxy-1-mesityl-4-methylpent-1-en-3-one, either enantiomer can be accessed by using the catalyst shown or its enantiomer, both of which are available from Sigma-Aldrich.

其他說明

Expanded substrate scope and catalyst optimization for the catalytic kinetic resolution of N-heterocycles

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H302
• 防範說明: P301 + P312 + P330
• 危險分類: Acute Tox. 4 Oral
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable