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形狀
solid
mp
140-145 °C
SMILES 字串
BrCc1ccc2ccc3cccc4ccc1c2c34
InChI
1S/C17H11Br/c18-10-14-7-6-13-5-4-11-2-1-3-12-8-9-15(14)17(13)16(11)12/h1-9H,10H2
InChI 密鑰
UGMXRPVWWWDPFC-UHFFFAOYSA-N
應用
1-(溴甲基)芘广泛用于合成荧光基团,用于多种分析物的荧光传感,包括生理pH下的金属离子(如cd2+、zn2+和三磷酸腺苷(ATP))传感。它也用于合成光引发剂(PI),用于丙烯酸酯的自由基聚合以及环氧-硅树脂和羟基醚的阳离子聚合。
訊號詞
Danger
危險聲明
危險分類
Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
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A pyrenyl-appended triazole-based calix [4] arene as a fluorescent sensor for Cd2+ and Zn2+.
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A tong-like fluorescence sensor for metal ions: perfect conformational switch of hinge sugar by pyrene stacking.
Organic & Biomolecular Chemistry, 2(24), 3548-3556 (2004)
New insights into radical and cationic polymerizations upon visible light exposure: role of novel photoinitiator systems based on the pyrene chromophore.
Polym. Chem., 4(5), 1625-1634 (2013)
Unique sandwich stacking of pyrene-adenine-pyrene for selective and ratiometric fluorescent sensing of ATP at physiological pH.
Journal of the American Chemical Society, 131(42), 15528-15533 (2009)
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 228, 117725-117725 (2019-11-14)
We developed PIM, a pyrene-based fluorescence sensor bearing an imidazole moiety and a carbonyl group as the binding sites for Fe3+ ions. The pyrene-based control compounds 1 and 2 were synthesized to demonstrate the structure-activity relationships. Compound 1, which contained
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