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Merck

745499

Sigma-Aldrich

Zinc trifluoroethanesulfinate

别名:

Baran TFES Reagent, Baran Trifluoroethylation Reagent, Bis(((2,2,2-trifluoroethyl)sulfinyl)oxy)zinc, TFES

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About This Item

经验公式(希尔记法):
C4H4F6O4S2Zn
分子量:
359.58
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22

形狀

solid

反應適用性

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

mp

114-120 °C

SMILES 字串

O=S(O[Zn]OS(CC(F)(F)F)=O)CC(F)(F)F

InChI

1S/2C2H3F3O2S.Zn/c2*3-2(4,5)1-8(6)7;/h2*1H2,(H,6,7);/q;;+2/p-2

InChI 密鑰

PUGHSSOALZPRJD-UHFFFAOYSA-L

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一般說明

Zinc trifluoroethanesulfinate (TFES) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

聯結

Frequently Asked Questions are available for this Product.

其他說明

Previously sold under product number L511234

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Fionn O'Hara et al.
Journal of the American Chemical Society, 135(32), 12122-12134 (2013-07-19)
Radical addition processes can be ideally suited for the direct functionalization of heteroaromatic bases, yet these processes are only sparsely used due to the perception of poor or unreliable control of regiochemistry. A systematic investigation of factors affecting the regiochemistry
Yuta Fujiwara et al.
Nature, 492(7427), 95-99 (2012-12-04)
Nitrogen-rich heterocyclic compounds have had a profound effect on human health because these chemical motifs are found in a large number of drugs used to combat a broad range of diseases and pathophysiological conditions. Advances in transition-metal-mediated cross-coupling have simplified

商品

Rapidly diversify (hetero)aromatic scaffolds for chemical industry needs amid resource and time constraints, ensuring efficiency.

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