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Merck
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文件

731277

Sigma-Aldrich

2-氰基-2-丙基-4-氰基苯二硫代碳酸酯

98% (HPLC)

别名:

2-氰基丙基-4-氰基二硫代苯甲酸酯, 4-氰基苯硫代碳酸-1-氰基-1-甲基乙酯

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About This Item

经验公式（希尔记法）:
C12H10N2S2
CAS号:
851729-48-1
分子量:
246.35
MDL號碼:
MFCD18252680
分類程式碼代碼:
12352100
PubChem物質ID:
329764639
NACRES:
NA.23

化驗

98% (HPLC)

形狀

solid

mp

122-127 °C

SMILES 字串

CC(C)(SC(=S)c1ccc(cc1)C#N)C#N

InChI

1S/C12H10N2S2/c1-12(2,8-14)16-11(15)10-5-3-9(7-13)4-6-10/h3-6H,1-2H3

InChI 密鑰

GLQSCQVGVPUIPC-UHFFFAOYSA-N

相关类别

一般說明

需要帮助选择正确的可逆加成-断裂链转移剂? 请翻阅单体目录里面的RAFT部分兼容性表格.

應用

用于可控自由基聚合的可逆加成 - 断裂链转移剂;特别适合苯乙烯，丙烯酸酯和丙烯酰胺单体聚合。链转移剂（CTA）

法律資訊

销售仅用于研究目的:请访问sigma-aldrich.com/raftlicense 专利: WO98/01478; WO99/311444

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H317

防範說明

P280

危險分類

Skin Sens. 1

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

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RAFT Agent Design and Synthesis
Keddie, D. J.; et al.
Macromolecules, 45, 5321-5342 (2012)
Massimo Benaglia et al.
Journal of the American Chemical Society, 131(20), 6914-6915 (2009-05-01)
The polymerization of most monomers that are polymerizable by radical polymerization can be controlled by the reversible addition-fragmentation chain transfer (RAFT) process. However, it is usually required that the RAFT agent be selected according to the types of monomer being

商品

Convert to mPAGE™ Gels for Improved Results

RAFT polymerization uses commercial agents to control polymer properties without cytotoxic heavy metals like ATRP.

逆加成-断裂链转移 (RAFT)聚合

RAFT（可逆加成断裂链转移）聚合是一种可逆的去活化自由基聚合（RDRP），是给自由基聚合赋予活性的通用方法之一。

RAFT Polymerization

RAFT polymerization offers living characteristics to radical polymerization, contributing versatility to reversible deactivation radical polymerization methods.

Protein- and Peptide- Polymer Conjugates by RAFT Polymerization

The modification of biomacromolecules, such as peptides and proteins, through the attachment of synthetic polymers has led to a new family of highly advanced biomaterials with enhanced properties.

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实验方案

RAFT聚合反应操作步骤

RAFT（可逆加成-断裂链转移）是一种活性自由基聚合反应，在有适合的连转移（RAFT）试剂存在下发生的非传统的取代单体自由基聚合反应。

RAFT Polymerization Procedures

RAFT polymerization offers precise control, enabling tailored synthesis of complex polymer structures.

Typical Procedures for Polymerizing via RAFT

We presents an article featuring procedures that describe polymerization of methyl methacrylate and vinyl acetate homopolymers and a block copolymer as performed by researchers at CSIRO.

Concepts and Tools for RAFT Polymerization

We present an article about RAFT, or Reversible Addition/Fragmentation Chain Transfer, which is a form of living radical polymerization.

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