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730416

S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine

Name: S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine
Brand: ALDRICH

97%

别名:

N-[(fluorophenylmethyl)oxidophenyl-λ₄-sulfanylidene]-4-methyl-benzenesulfonamide

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About This Item

经验公式（希尔记法）:

C₂₀H₁₈FNO₃S₂

CAS号:

1260143-68-7

分子量:

403.49

MDL编号:

MFCD18910698

UNSPSC代码:

12352101

PubChem化学物质编号:

329764564

NACRES:

NA.22

方案

97%

表单

solid

mp

148-154 °C

SMILES字符串

Cc1ccc(cc1)S(=O)(=O)N=S(=O)(C(F)c2ccccc2)c3ccccc3

InChI

1S/C20H18FNO3S2/c1-16-12-14-19(15-13-16)27(24,25)22-26(23,18-10-6-3-7-11-18)20(21)17-8-4-2-5-9-17/h2-15,20H,1H3

InChI key

ZAGQEXRRSCLLFW-UHFFFAOYSA-N

应用

S-(α-Fluorobenzyl)-S-phenyl-N-(p-tolylsulfonyl)sulfoximine can be used as a reagent for the synthesis of monofluorinated epoxides byO-cyclization reaction with ketones in the presence of a strong base.

象形图

GHS07

警示用语：

Warning

危险声明

H315,H319,H335,H413

预防措施声明

P261 - P305 + P351 + P338

危险分类

Aquatic Chronic 4 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

储存分类代码

13 - Non Combustible Solids

WGK

WGK 1

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

MKBF7464V

MKBF7464

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Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from α-Fluorosulfoximines

Zhang W and Hu J

advanced synthesis and catalysis, 352(16), 2799-2804 (2010)

Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from α-Fluorosulfoximines

Zhang W and Hu J

Advanced Synthesis & Catalysis, 352(16), 2799-2804 (2010)

Efficient Synthesis and Ring-Opening Reactions of Monofluorinated Epoxides Derived from a-Fluorosulfoximines

Zhang, W.; Hu, J.

Advanced Synthesis & Catalysis, 352, 2799-2804 (2010)