728357

N-[(1R,2R)-2-(1-哌啶基）环己基]-N′-[4-（三氟甲基）苯基]四酰胺

95%

• 别名: 3-{[(1R,2R)-2-(1-Piperidinyl)cyclohexyl]amino}-4-{[4-(trifluoromethyl)phenyl]amino}-3-cyclobutene-1,2-dione, Rawal Squaramide Organocatalyst
• 经验公式（希尔记法）: C₂₂H₂₆F₃N₃O₂
• CAS号: 1211565-08-0
• 分子量: 421.46
• MDL號碼: MFCD18827464
• 分類程式碼代碼: 12352005
• PubChem物質ID: 329764393
• NACRES: NA.22

属性

• 品質等級: 100
• 化驗: ≥94.5% (HPLC); 95%
• 形狀: powder
• 光學活性: [α]/D -42.0±2.0°, c = 1 in DMSO
• 雜質: ≤2.0% pyridine
• SMILES 字串: FC(F)(F)c1ccc(NC2=C(N[C@@H]3CCCC[C@H]3N4CCCCC4)C(=O)C2=O)cc1
• InChI: 1S/C22H26F3N3O2/c23-22(24,25)14-8-10-15(11-9-14)26-18-19(21(30)20(18)29)27-16-6-2-3-7-17(16)28-12-4-1-5-13-28/h8-11,16-17,26-27H,1-7,12-13H2/t16-,17-/m1/s1
• InChI 密鑰: JRSCPJJNZMRAQS-IAGOWNOFSA-N

说明

應用

Catalyst for enantioselective Michael addition.

It can act as a catalyst for the asymmetric tandem aza-Michael addition-protonation between 1-nitro cyclohexene and 4-methoxyaniline to form the corresponding α-arylamino-β-nitro cyclohexane in a 35:65 trans/cis mixture.

包裝

Bottomless glass bottle. Contents are inside inserted fused cone.

安全信息

• 象形圖: GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H315,H318,H335
• 防範說明: P280 - P302 + P352 - P305 + P351 + P338 + P310
• 危險分類: Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable