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形狀
solution
反應適用性
core: iron
reagent type: catalyst
環保替代產品特色
Safer Solvents and Auxiliaries
Use of Renewable Feedstocks
Catalysis
Learn more about the Principles of Green Chemistry.
sustainability
Greener Alternative Product
濃度
0.2 M in 2-methyltetrahydrofuran
折射率
n20/D 1.414
密度
0.868 g/mL at 25 °C
環保替代類別
, Aligned
SMILES 字串
Cl[Fe](Cl)Cl
InChI
1S/3ClH.Fe/h3*1H;/q;;;+3/p-3
InChI 密鑰
RBTARNINKXHZNM-UHFFFAOYSA-K
一般說明
我们致力于为您带来更加绿色的替代产品,这些产品遵守一项或多项绿色化学12项原则。凭借独特的性质,如无毒、低成本、丰度高、选择性高,FeCl3可用于许多生物质转化过程。该产品在2-甲基四氢呋喃中的浓度为0.2 M,因此符合“更安全的溶剂和助剂”、“可再生原料的使用”原则,并提高了催化效率。点击此处以获取更多信息。
應用
溶于绿色溶剂2-甲基四氢呋喃 (2-MeTHF) 中的氯化铁(III)可用于:
2-甲基四氢呋喃(2-MeTHF): 一种生物质衍生的溶剂,广泛应用于有机化学
- 作为酚醛偶联反应的温和氧化剂
- 用于芳基锂和酮烯醇化物的二聚体化
- 作为一种温和的路易斯酸催化剂催化烯反应
- Nazarov环化、迈克尔加成和丙酮化反应
2-甲基四氢呋喃(2-MeTHF): 一种生物质衍生的溶剂,广泛应用于有机化学
訊號詞
Danger
危險分類
Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Met. Corr. 1 - Skin Irrit. 2
安全危害
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 2
閃點(°F)
14.0 °F - closed cup
閃點(°C)
-10.0 °C - closed cup
Chemical Society reviews, 38(9), 2730-2744 (2009-08-20)
In this critical review, the use of iron(III) chloride in oxidative C-C couplings of arenes and related unsaturated compounds is presented and reviewed. The approach allows highly selective dimerisations of phenol derivatives, naphthols, and heterocyclic compounds. Sequential couplings give access
Clinica chimica acta; international journal of clinical chemistry, 438, 337-341 (2014-10-05)
Insulin-like growth factor binding protein-1 (IGFBP-1) constitutes a subgroup of the insulin-like growth factor binding protein systems, and its concentration in amniotic fluid is 100-1000 times higher than the concentration in other body fluids. The aim of this study was
Colloids and surfaces. B, Biointerfaces, 109, 74-81 (2013-04-27)
The early stages of the formation of inorganic aggregates, composed of iron compounds at the solution-air interface, were investigated in situ. The properties of the solution-air interface were changed by using different Langmuir layers. In order to get insight into
Organic letters, 15(3), 429-431 (2013-01-16)
A novel approach was developed for the synthesis of highly substituted indene derivatives, using an FeCl(3) catalyzed Prins-type cyclization reaction which was further applied in the total synthesis of jungianol and epi-jungianol.
Angewandte Chemie (International ed. in English), 51(50), 12546-12550 (2012-11-06)
IRONic electrophilic indoles! The C3-regioselective hydroarylation of N-acetyl indoles with aromatic nucleophiles mediated by FeCl(3) features a rare example of the electrophilic reactivity of the indole core in a Friedel-Crafts reaction. This indole umpolung allows us straightforward access to the
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