708844

(1S,2S)-N,N′-双(2-乙酰-3-氧代-2-亚丁烯基)-1,2-二均三甲苯基乙二胺合钴(II)

• 别名: (S,S)-AMAC
• 经验公式（希尔记法）: C₃₂H₃₈CoN₂O₄
• CAS号: 259259-80-8
• 分子量: 573.59
• MDL號碼: MFCD06797062
• 分類程式碼代碼: 12352000
• PubChem物質ID: 329762829
• NACRES: NA.22

属性

• 形狀: solid
• 品質等級: 100
• 光學活性: [α]/D −309°, c = 0.1 in chloroform
• mp: 242-246 °C
• 官能基: ketone
• SMILES 字串: CC(=O)C1=C(C)O[Co]OC(C)=C(\C=N\[C@H]([C@@H](\N=C\1)c2c(C)cc(C)cc2C)c3c(C)cc(C)cc3C)C(C)=O
• InChI: 1S/C32H40N2O4.Co/c1-17-11-19(3)29(20(4)12-17)31(33-15-27(23(7)35)24(8)36)32(34-16-28(25(9)37)26(10)38)30-21(5)13-18(2)14-22(30)6;/h11-16,31-32,35,37H,1-10H3;/q;+2/p-2/b27-23+,28-25+,33-15+,34-16+;/t31-,32-;/m0./s1
• InChI 密鑰: PHCQQLMRNZRDJA-OZXAGROVSA-L

说明

應用

Catalyst for:

• Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
• Enantioselective borohydride reduction
• Preparation of ß-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
• Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones

安全信息

• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)