708763

[(S)-(-)-2,2′-双(二-对甲苯基膦)-1,1′-联萘]氯化钯(II)

• 别名: [PdCl₂{(S)-4-tolylbinap}]
• 经验公式（希尔记法）: C₄₈H₄₀Cl₂P₂Pd
• CAS号: 215597-19-6
• 分子量: 856.10
• MDL號碼: MFCD11656205
• 分類程式碼代碼: 12352005
• PubChem物質ID: 329762823

属性

• 形狀: solid
• mp: >300 °C
• 官能基: phosphine
• SMILES 字串: Cl[Pd]Cl.Cc1ccc(cc1)P(c2ccc(C)cc2)c3ccc4ccccc4c3-c5c(ccc6ccccc56)P(c7ccc(C)cc7)c8ccc(C)cc8
• InChI: 1S/C48H40P2.2ClH.Pd/c1-33-13-23-39(24-14-33)49(40-25-15-34(2)16-26-40)45-31-21-37-9-5-7-11-43(37)47(45)48-44-12-8-6-10-38(44)22-32-46(48)50(41-27-17-35(3)18-28-41)42-29-19-36(4)20-30-42;;;/h5-32H,1-4H3;2*1H;/q;;;+2/p-2
• InChI 密鑰: ADMKISPNGKUJAU-UHFFFAOYSA-L

说明

應用

Catalyst for:

• Stereoselective preparation of hydroxymethyldihydronaphthalenone via alkylative ring opening of oxabenzonorbornadiene with (PhMe2SiCH2)2Zn followed by hydrogenation and Tamao-Fleming oxidation
• Asymmetric synthesis of cyclopentylindanes via cyclization of bromo- and trifluoromethanesulfonyloxyphenylheptenylmalonate

安全信息

• 儲存類別代碼: 13 - Non Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)