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化驗
≥99.0% (C)
mp
100-103 °C
儲存溫度
2-8°C
SMILES 字串
CS(=O)(=O)CCOC(=O)Oc1ccc(cc1)[N+]([O-])=O
其他說明
引入 MSOC 基团的试剂,MSOC 是多功能氨基保护官能团,其具有以下特性:优良的酸稳定性和碱不稳定性,以及可提高极性溶剂中的溶解度的强极性。MSOC 不发生氢化反应,但不会使催化剂中毒
[Hormone-receptor interactions. Syntheses of alpha-melanotropin and of informational sequences thereof with the aid of alcali-labile protecting groups (author's transl)].
Helvetica chimica acta, 58(7), 2106-2129 (1975-11-05)
Helvetica Chimica Acta, 60, 2895-2895 (1977)
International journal of peptide and protein research, 7(4), 295-305 (1975-01-01)
A new amino protecting group, the methylsulfonylethyloxycarbonyl (Msc) group, is described which combines well with other familiar groups (benzyloxycarbonyl, t-butyloxycarbonyl) in peptide syntheses. Its main characteristics are an extreme acid stability, a high base lability and a high polarity which
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