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化驗
≥98.0% (HPLC)
反應適用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: ligand
mp
78-82 °C
官能基
phosphine
儲存溫度
2-8°C
SMILES 字串
CCC(C)(C)c1cccc(n1)P(c2ccccc2)c3ccccc3
InChI
1S/C22H24NP/c1-4-22(2,3)20-16-11-17-21(23-20)24(18-12-7-5-8-13-18)19-14-9-6-10-15-19/h5-17H,4H2,1-3H3
InChI 密鑰
ZEQMNGUCEYRQRF-UHFFFAOYSA-N
應用
用于催化:
- 寡聚1,4-二醇的区域选择性合成
- 反马氏水和反应
危險聲明
危險分類
Aquatic Chronic 4
儲存類別代碼
13 - Non Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Organic letters, 8(25), 5853-5856 (2006-12-01)
The anti-Markovnikov hydration of terminal alkynes to give aldehydes is catalyzed by complexes derived in situ from air-stable [CpRu(eta6-naphthalene)]PF6 (C) and 6-aryl-2-diphenylphosphinopyridines (L). Ligands L are readily available from a modular synthesis. Increasing the size of the ligand C-6 aryl
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