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About This Item
经验公式(希尔记法):
C10H10O3
CAS号:
分子量:
178.18
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
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方案
97%
折射率
n20/D 1.4990 (lit.)
沸点
67-70 °C/0.3 mmHg (lit.)
密度
1.096 g/mL at 25 °C (lit.)
官能团
carbonate
phenoxy
SMILES字符串
C=CCOC(=O)Oc1ccccc1
InChI
1S/C10H10O3/c1-2-8-12-10(11)13-9-6-4-3-5-7-9/h2-7H,1,8H2
InChI key
ORUWSEKEVGOAQR-UHFFFAOYSA-N
一般描述
Allyl phenyl carbonate can be obtained via by reacting phenyl chloroformate and allyl alcohol in presence of pyridine.
应用
Allyl phenyl carbonate can react with (2-alkynyl)phenylisocyanate, catalyzed P(0)/Cu(I) system to give the corresponding indole.
警示用语:
Warning
危险声明
危险分类
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Sens. 1
储存分类代码
10 - Combustible liquids
WGK
WGK 3
闪点(°F)
>230.0 °F
闪点(°C)
> 110 °C
个人防护装备
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
"A New Pd0?CuI Bimetallic Catalyst for the Synthesis of Indoles from Isocyanates and Allyl Carbonates"
Kamijo S and Yamamoto Y
Angewandte Chemie (Weinheim an der Bergstrasse, Germany), 114(17), 3364-3367 (2002)
?Selective synthesis of carbamate protected polyamines using alkyl phenyl carbonates"
Pittelkow M, et al.
Synthesis, 2002(15), 2195- 2202 (2002)
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