555142

1-二苯基膦基-1′-(二叔丁基膦基)二茂铁

• 经验公式（希尔记法）: C₃₀H₃₆FeP₂
• CAS号: 95408-38-1
• 分子量: 514.40
• MDL编号: MFCD03701526
• UNSPSC代码: 12352005
• PubChem化学物质编号: 24879174
• NACRES: NA.22

属性

• 表单: solid
• 质量水平: 100
• 反应适用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand; reaction type: Coupling Reactions
• mp: 75-79 °C (lit.)
• 官能团: phosphine
• SMILES字符串: [Fe].CC(C)(C)P([C]1[CH][CH][CH][CH]1)C(C)(C)C.[CH]2[CH][CH][C]([CH]2)P(c3ccccc3)c4ccccc4
• InChI: 1S/C17H14P.C13H22P.Fe/c1-3-9-15(10-4-1)18(17-13-7-8-14-17)16-11-5-2-6-12-16;1-12(2,3)14(13(4,5)6)11-9-7-8-10-11;/h1-14H;7-10H,1-6H3;
• InChI key: GQIMIFFIUZZVMJ-UHFFFAOYSA-N

说明

应用

• Catalyst in microwave-assisted preparation of aryl-alkyl ethers via palladium-catalyzed Hiyama coupling of alkoxysilanes with aryl bromides or aryl chlorides
• Ligand for catalytic isomerization of methylbutenenitrile via nickel systems
• Ligand for ruthenium alkylidene complexes for catalysis of metathesis reactions and catalytic norbornene polymerization

安全信息

• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: Eyeshields, Gloves, type N95 (US)