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化驗
98%
折射率
n20/D 1.396 (lit.)
bp
133 °C (lit.)
密度
1.212 g/mL at 25 °C (lit.)
SMILES 字串
CCOC(=O)C(F)Cl
InChI
1S/C4H6ClFO2/c1-2-8-4(7)3(5)6/h3H,2H2,1H3
InChI 密鑰
WUHVJSONZHSDFC-UHFFFAOYSA-N
應用
Ethyl chlorofluoroacetate may be used in the synthesis of:
- chlorofluoroacetamide
- ethyl α-fluoro silyl enol ether
- chlorofluoroacetyl chloride
訊號詞
Danger
危險聲明
危險分類
Flam. Liq. 3 - Skin Corr. 1B
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
125.0 °F - closed cup
閃點(°C)
51.67 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
One-step method for converting esters to acyl chlorides.
The Journal of Organic Chemistry, 44(13), 2291-2292 (1979)
The Journal of organic chemistry, 67(10), 3231-3234 (2002-05-11)
Ethyl alpha-fluoro silyl enol ether is stereoselectively synthesized in high yield from inexpensive chlorofluoroacetate and Mg (or Zn) in DMF (or HMPA). Lewis acid promoted aldol reaction of this enol ether with aldehydes and ketones gives alpha-fluoro-beta-hydroxy esters in good
The preparation of some derivatives of chlorofluoroacetic acid.
Journal of the American Chemical Society, 71(1), 3278-3285 (1949)
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