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Merck

539147

Sigma-Aldrich

氯氟乙酸乙酯

98%

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About This Item

线性分子式:
Cl(F)CHCO2C2H5
CAS号:
分子量:
140.54
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

折射率

n20/D 1.396 (lit.)

bp

133 °C (lit.)

密度

1.212 g/mL at 25 °C (lit.)

SMILES 字串

CCOC(=O)C(F)Cl

InChI

1S/C4H6ClFO2/c1-2-8-4(7)3(5)6/h3H,2H2,1H3

InChI 密鑰

WUHVJSONZHSDFC-UHFFFAOYSA-N

應用

Ethyl chlorofluoroacetate may be used in the synthesis of:
  • chlorofluoroacetamide
  • ethyl α-fluoro silyl enol ether
  • chlorofluoroacetyl chloride

象形圖

FlameCorrosion

訊號詞

Danger

危險聲明

危險分類

Flam. Liq. 3 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

125.0 °F - closed cup

閃點(°C)

51.67 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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One-step method for converting esters to acyl chlorides.
Middleton WJ.
The Journal of Organic Chemistry, 44(13), 2291-2292 (1979)
Xiao-Ting Huang et al.
The Journal of organic chemistry, 67(10), 3231-3234 (2002-05-11)
Ethyl alpha-fluoro silyl enol ether is stereoselectively synthesized in high yield from inexpensive chlorofluoroacetate and Mg (or Zn) in DMF (or HMPA). Lewis acid promoted aldol reaction of this enol ether with aldehydes and ketones gives alpha-fluoro-beta-hydroxy esters in good
The preparation of some derivatives of chlorofluoroacetic acid.
Young JA and Tarrant P.
Journal of the American Chemical Society, 71(1), 3278-3285 (1949)

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