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Merck

537764

Sigma-Aldrich

1-己炔-3-醇

90%, technical grade

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About This Item

经验公式(希尔记法):
C6H10O
CAS号:
分子量:
98.14
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

等級

technical grade

化驗

90%

折射率

n20/D 1.431

bp

118 °C

密度

0.873 g/mL at 25 °C

SMILES 字串

CCCC(O)C#C

InChI

1S/C6H10O/c1-3-5-6(7)4-2/h2,6-7H,3,5H2,1H3

InChI 密鑰

LTFTWJYRQNTCHI-UHFFFAOYSA-N

一般說明

1-Hexyn-3-ol is a terminal propargylic alcohol. It undergoes microwave-accelerated coupling-isomerization reaction (MACIR) with (hetero)aryl halides to afford the corresponding enone.

應用

1-Hexyn-3-ol may be used in the synthesis of racemic 3-hydroxy-2-hexanone. It may also be used in the preparation of 1,2,3-triazoles.

訊號詞

Danger

危險分類

Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

117.0 °F

閃點(°C)

47.2 °C

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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访问文档库

Yunfan Zou et al.
Journal of chemical ecology, 41(7), 670-677 (2015-07-08)
We report the identification of a novel pheromone structure from males of the cerambycid beetle Tylonotus bimaculatus Haldeman (Cerambycinae: Hesperophanini), a species native to eastern North America. Volatiles collected from adult males contained (2S,4E)-2-hydroxyoct-4-en-3-one (71%), (3R,4E)-3-hydroxyoct-4-en-2-one (15%), (E)-4-octen-2,3-dione (13%), and
Microwave-Accelerated Coupling-Isomerization Reaction (MACIR)?A General Coupling-Isomerization Synthesis of 1, 3-Diarylprop-2-en-1-ones.
Muller TJJ.
Advanced Synthesis & Catalysis, 348(18), 2565-2570 (2006)
Synthesis of New Carbohydrate Derivatives Via 1, 3-Dipolarcycloaddition Reaction.
Sharba AHK, et al.
Journal of Al-Nahrain University, 14(2), 9S-9S (2011)
The synthesis of 1, 1'-disubstituted bis-cyclopropanes by the reaction of substituted propargylic alcohols with CH 2 I 2?R 3 Al.
Ramazanov IR, et al.
Tetrahedron Letters, 50(29), 4233-4235 (2009)

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