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464147

Sigma-Aldrich

4,5-二甲氧基-3-碘苯甲醛

97%

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About This Item

线性分子式:
IC6H2(OCH3)2CHO
CAS号:
32024-15-0
分子量:
292.07
MDL號碼:
MFCD00674091
分類程式碼代碼:
12352100
PubChem物質ID:
24870143
NACRES:
NA.22

化驗

97%

mp

69-72 °C (lit.)

官能基

aldehyde
iodo

SMILES 字串

COc1cc(C=O)cc(I)c1OC

InChI

1S/C9H9IO3/c1-12-8-4-6(5-11)3-7(10)9(8)13-2/h3-5H,1-2H3

InChI 密鑰

MVPNBXPAUYYZAF-UHFFFAOYSA-N

一般說明

3-Iodo-4,5-dimethoxybenzaldehyde is an aryl iodide having an aldehyde group. It can be synthesized starting from 3,4-dihydroxy-5-iodobenzaldehyde.

應用

3-Iodo-4,5-dimethoxybenzaldehyde was used in the preparation of 3-iodo-4,4′,5-trimethoxy-3′-O-tert-butyldiphenylsilyl-Z-stilbene and 3-iodo-4,4′,5-trimethoxy-3′-O-tert-butyldiphenylsilyl-E-stilbene. It may be used for the synthesis of chloropeptin I and chloropeptin II.

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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分析证书(COA)

Lot/Batch Number
07024JJ
00103PD
13228MQ

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George R Pettit et al.
Journal of natural products, 75(3), 385-393 (2012-02-14)
Toward the objective of designing a structurally modified analogue of the combretastatin A-4 phosphate prodrug (1b) with the potential for increased specificity toward thyroid carcinoma, synthesis of a series of iodocombstatin phosphate (11a-h) and diiodocombstatin phosphate prodrugs (12a-h) has been
Joie Garfunkle et al.
Journal of the American Chemical Society, 131(44), 16036-16038 (2009-10-21)
The first total synthesis of chloropeptin II (1, complestatin) is disclosed. Key elements of the approach include the use of an intramolecular Larock indole synthesis for the initial macrocyclization, adopting conditions that permit utilization of a 2-bromoaniline, incorporating a terminal
Approaches to iodinated derivatives of vanillin and isovanillin.
Nammalwar B, et al.
Organic preparations and procedures international, 44(2), 146-146 (2012)
Nucleophilic catalysis of the iodine-zinc exchange reaction: preparation of highly functionalized diaryl zinc compounds.
Florian F Kneisel et al.
Angewandte Chemie (International ed. in English), 43(8), 1017-1021 (2004-02-18)

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