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Merck

452114

Sigma-Aldrich

溴氟乙酸乙酯

97%

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About This Item

线性分子式:
BrCH(F)CO2C2H5
CAS号:
分子量:
184.99
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

97%

折射率

n20/D 1.424 (lit.)

bp

154 °C (lit.)

密度

1.565 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

CCOC(=O)C(F)Br

InChI

1S/C4H6BrFO2/c1-2-8-4(7)3(5)6/h3H,2H2,1H3

InChI 密鑰

ULNDTPIRBQGESN-UHFFFAOYSA-N

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象形圖

Exclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

159.8 °F - closed cup

閃點(°C)

71 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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分析证书(COA)

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The presence of catalytic amounts of CeCl(3) improves yields and simplifies procedure in the Reformatsky reactions of ethyl bromofluoroacetate with aldehydes and ketones to generate diastereomeric mixtures of alpha-fluoro-beta-hydroxy esters, some of which can be separated by crystallization or column
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The synthesis of highly functionalized monofluorinated cyclopropanes based on a Michael Initiated Ring Closure (MIRC) reaction has been developed. The addition of quaternary ammonium salts derived from ethyl bromofluoroacetate on a panel of electron deficient alkenes followed by cyclization gave

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