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化驗
97%
形狀
liquid
折射率
n20/D 1.463 (lit.)
bp
130-131 °C/14 mmHg (lit.)
密度
1.362 g/mL at 25 °C (lit.)
儲存溫度
2-8°C
SMILES 字串
CCOP(=O)(OCC)C(Cl)(Cl)Cl
InChI
1S/C5H10Cl3O3P/c1-3-10-12(9,11-4-2)5(6,7)8/h3-4H2,1-2H3
InChI 密鑰
RVAQSYWDOSHWGP-UHFFFAOYSA-N
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一般說明
Addition reaction of diethyl (trichloromethyl)phosphonate to olefins by non-chain catalytic reactions catalyzed by copper amine complexes has been reported. Irradiation of diethyl (trichloromethyl)phosphonate in MeCN is reported to afford corresponding monoesters and olefins, via photochemical type II elimination reaction.
應用
Diethyl (trichloromethyl)phosphonate may be used in the synthesis of chlorovinyl phosphonates via reaction with aldehydes and ketones.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
235.4 °F - closed cup
閃點(°C)
113 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Addition of diethyl trichloromethylphosphonate to olefins catalysed by copper complexes.
Tetrahedron Letters, 35(21), 3537-3538 (1994)
A novel synthesis of phosphonates from diethyl (trichloromethyl) phosphonate.
The Journal of Organic Chemistry, 59(!6), 4548-4550 (1994)
Photochemical type I and II elimination reactions of dialkyl (trichloromethyl) phosphonates.
Bulletin of the Chemical Society of Japan, 53(5), 1421-1424 (1980)
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