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Merck

371785

Sigma-Aldrich

5-羟基间苯二甲酸二甲酯

98%

别名:

5-羟基苯-1,3-二羧酸二甲酯

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About This Item

线性分子式:
HOC6H3-1,3-(CO2CH3)2
CAS号:
分子量:
210.18
Beilstein:
2650120
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

powder

mp

162-164 °C (lit.)

SMILES 字串

COC(=O)c1cc(O)cc(c1)C(=O)OC

InChI

1S/C10H10O5/c1-14-9(12)6-3-7(10(13)15-2)5-8(11)4-6/h3-5,11H,1-2H3

InChI 密鑰

DOSDTCPDBPRFHQ-UHFFFAOYSA-N

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一般說明

5-羟基间苯二甲酸二甲酯与烯丙基缩水甘油醚进行碱催化的亲核环氧乙烷开环加成反应,生成间苯二甲酸的 5-取代衍生物。已经研究了第三组分(即一系列的 1,ω-链烷二醇)对 5-羟基间苯二甲酸二甲酯与聚乙二醇的共聚反应的影响。已经报道了脂肪酶催化 5-羟基间苯二甲酸二甲酯与聚乙二醇的缩聚反应。

應用

衍生自 5-羟基间苯二甲酸二甲酯的新型结构单元已用于通过 O-烯丙基化/Claisen 重排反应来制备空间拥挤的聚醚树枝状分子。5-羟基间苯二甲酸二甲酯可用于制备:
  • 环磷腈的双(phebox)衍生物
  • 5- {2- [2-(2-甲氧基乙氧基)乙氧基]乙氧基}苯-1,3-二羧酸二甲酯
  • 带有三乙二醇型极性头基的富勒烯衍生物

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves


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