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化驗
98%
形狀
powder
mp
162-164 °C (lit.)
SMILES 字串
COC(=O)c1cc(O)cc(c1)C(=O)OC
InChI
1S/C10H10O5/c1-14-9(12)6-3-7(10(13)15-2)5-8(11)4-6/h3-5,11H,1-2H3
InChI 密鑰
DOSDTCPDBPRFHQ-UHFFFAOYSA-N
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一般說明
5-羟基间苯二甲酸二甲酯与烯丙基缩水甘油醚进行碱催化的亲核环氧乙烷开环加成反应,生成间苯二甲酸的 5-取代衍生物。已经研究了第三组分(即一系列的 1,ω-链烷二醇)对 5-羟基间苯二甲酸二甲酯与聚乙二醇的共聚反应的影响。已经报道了脂肪酶催化 5-羟基间苯二甲酸二甲酯与聚乙二醇的缩聚反应。
應用
衍生自 5-羟基间苯二甲酸二甲酯的新型结构单元已用于通过 O-烯丙基化/Claisen 重排反应来制备空间拥挤的聚醚树枝状分子。5-羟基间苯二甲酸二甲酯可用于制备:
- 环磷腈的双(phebox)衍生物
- 5- {2- [2-(2-甲氧基乙氧基)乙氧基]乙氧基}苯-1,3-二羧酸二甲酯
- 带有三乙二醇型极性头基的富勒烯衍生物
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Biocatalytic ?green? Synthesis of PEG-based aromatic polyesters: Optimization of the substrate and reaction conditions.
Green Chemistry, 6(10), 516-520 (2004)
Organic & biomolecular chemistry, 10(24), 4788-4794 (2012-05-19)
Up to third-generation sterically crowded polyether dendrons were prepared on a solid support, using a novel building block derived from dimethyl 5-hydroxyisophthalate via O-allylation/Claisen rearrangement key steps. These dendrons underwent smooth disassembly to monomers, when subjected to acidic solution. The
Molecular diversity, 6(3-4), 287-295 (2004-04-08)
The use of enzymes in synthetic applications has increased dramatically in the recent years and the field of polymer science is part of this trend. Synthesis of a variety of polymers using lipase catalyzed (Candida antarctica) polymerization reactions has led
Tetrahedron letters, 55(36), 5078-5081 (2014-08-26)
In the course of development of novel capping ligands with variable steric factor, which will be used as an organic coating for metal oxide nanoparticles, a base-catalyzed nucleophilic oxirane ring-opening addition reaction between dimethyl 5-hydroxyisophthalate and allyl glycidyl ether was
Langmuir : the ACS journal of surfaces and colloids, 34(36), 10739-10747 (2018-08-16)
Physisorbed self-assembled monolayers (SAMs) have been suggested as potential models for three-dimensional (3D) crystallization. This work studies the effect of altering the chain length of 5-alkoxyisophthalic acid (C nISA) on self-assembled morphology in both two-dimensional (2D) and 3D to explore
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