369268

α-甲基二茂铁乙醇

97%

• 别名: 1-二茂铁基乙醇, α-羟乙基二茂铁
• 经验公式（希尔记法）: C₁₂H₁₄FeO
• CAS号: 1277-49-2
• 分子量: 230.08
• MDL號碼: MFCD00013752
• 分類程式碼代碼: 12352300
• PubChem物質ID: 24862812

属性

• 化驗: 97%
• 反應適用性: core: iron; reagent type: catalyst
• mp: 76-79 °C (lit.)
• SMILES 字串: [Fe].[CH]1[CH][CH][CH][CH]1.CC(O)[C]2[CH][CH][CH][CH]2
• InChI: 1S/C7H9O.C5H5.Fe/c1-6(8)7-4-2-3-5-7;1-2-4-5-3-1;/h2-6,8H,1H3;1-5H;
• InChI 密鑰: NJPGTUIMEAOISI-UHFFFAOYSA-N

说明

應用

• Ligand in titanium-catalyzed intermolecular hydroamination of terminal alkynes (Markovnikov vs. anti-Markovnikov addition)

Reactant for:

• Single-electron transfer living radical polymerization reactions
• Preparation of ferrocene-modified thiopyrimidines as anticancer agents
• Preparation of rersible addition-fragmentation chain transfer (RAFT) agent for RAFT polymerization of styrene

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves