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Merck

368539

Sigma-Aldrich

甲硫甲基苯基砜

99%

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About This Item

线性分子式:
C6H5SO2CH2SCH3
CAS号:
分子量:
202.29
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22

方案

99%

mp

85-87 °C (lit.)

SMILES字符串

CSCS(=O)(=O)c1ccccc1

InChI

1S/C8H10O2S2/c1-11-7-12(9,10)8-5-3-2-4-6-8/h2-6H,7H2,1H3

InChI key

XBGGZYQBIQAYII-UHFFFAOYSA-N

一般描述

Methylthiomethyl phenyl sulfone is a sulfone derivative.

应用

Methylthiomethyl phenyl sulfone may be employed:
  • as nucleophilic and electrophilic building block, in the asymmetric synthesis of 6-N-benzoyl-5′-O-benzyl-2′-deoxyadenosine and its anomer
  • in the synthesis of various multidentate methylthio arylethynes (MTA) derivatives
  • as starting reagent in the preparation of methylthio arylbutadiynes (Ar-C=C-C=C-SCH3)

象形图

Exclamation mark

警示用语:

Warning

危险声明

危险分类

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

靶器官

Respiratory system

储存分类代码

11 - Combustible Solids

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

个人防护装备

dust mask type N95 (US), Eyeshields, Gloves


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Efficient One-Pot Preparation of Methylthio Arylbutadiynes by Double Elimination Protocol.
Su Q, et al.
Synthetic Communications, 43(19), 2648-2655 (2019)
Rigid, conjugated and shaped arylethynes as mediators for the assembly of gold nanoparticles.
Yan H, et al.
Journal of Materials Chemistry, 21(6), 1890-1901 (2011)
B M Trost et al.
Carbohydrate research, 202, 1-12 (1990-07-15)
An asymmetric synthesis of 6-N-benzoyl-5'-O-benzyl-2'-deoxyadenosine and its a anomer from non-carbohydrate building blocks is achieved in 7 steps. The sequence builds the basic structures using bis(methylthio)methane and methylthiomethyl phenyl sulfone as both nucleophilic and electrophilic building blocks, a feature that

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