所有图片(1)
About This Item
线性分子式:
C6H5SO2CH2SCH3
CAS号:
分子量:
202.29
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
99%
mp
85-87 °C (lit.)
SMILES字符串
CSCS(=O)(=O)c1ccccc1
InChI
1S/C8H10O2S2/c1-11-7-12(9,10)8-5-3-2-4-6-8/h2-6H,7H2,1H3
InChI key
XBGGZYQBIQAYII-UHFFFAOYSA-N
一般描述
Methylthiomethyl phenyl sulfone is a sulfone derivative.
应用
Methylthiomethyl phenyl sulfone may be employed:
- as nucleophilic and electrophilic building block, in the asymmetric synthesis of 6-N-benzoyl-5′-O-benzyl-2′-deoxyadenosine and its anomer
- in the synthesis of various multidentate methylthio arylethynes (MTA) derivatives
- as starting reagent in the preparation of methylthio arylbutadiynes (Ar-C=C-C=C-SCH3)
警示用语:
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Efficient One-Pot Preparation of Methylthio Arylbutadiynes by Double Elimination Protocol.
Su Q, et al.
Synthetic Communications, 43(19), 2648-2655 (2019)
Rigid, conjugated and shaped arylethynes as mediators for the assembly of gold nanoparticles.
Yan H, et al.
Journal of Materials Chemistry, 21(6), 1890-1901 (2011)
B M Trost et al.
Carbohydrate research, 202, 1-12 (1990-07-15)
An asymmetric synthesis of 6-N-benzoyl-5'-O-benzyl-2'-deoxyadenosine and its a anomer from non-carbohydrate building blocks is achieved in 7 steps. The sequence builds the basic structures using bis(methylthio)methane and methylthiomethyl phenyl sulfone as both nucleophilic and electrophilic building blocks, a feature that
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