所有图片(1)
About This Item
线性分子式:
CH3COOC(CH3)2COBr
CAS号:
分子量:
209.04
Beilstein:
2432585
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
方案
≥95.0%
折射率
n20/D 1.457 (lit.)
沸点
75-77 °C/12 mmHg (lit.)
密度
1.431 g/mL at 25 °C (lit.)
储存温度
2-8°C
SMILES字符串
CC(=O)OC(C)(C)C(Br)=O
InChI
1S/C6H9BrO3/c1-4(8)10-6(2,3)5(7)9/h1-3H3
InChI key
OOKAXSHFTDPZHP-UHFFFAOYSA-N
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一般描述
1-Bromocarbonyl-1-methylethyl acetate (α-Acetoxyisobutyryl bromide) participates in the conversion of adenosine to trans-3′(2′)-bromo-2′(3′)-acetates, via glycosyl cleavage.
应用
用于邻二醇脱氧反应的试剂，也可用于由对应的系列核糖核苷制备 2′,3′-二脱氧胞嘧啶核苷和其他二脱氧核苷和脱氧核苷。
警示用语：
Danger
危险声明
危险分类
Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
靶器官
Respiratory system
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
235.4 °F - closed cup
闪点(°C)
113 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Aldrichimica Acta, 23, 83-83 (1990)
Biphenyl dioxygenase-catalysed cis-dihydroxylation of tricyclic azaarenes: chemoenzymatic synthesis of arene oxide metabolites and furoquinoline alkaloids.
Boyd DR, et al.
Royal Society of Chemistry Advances, 3(27), 10944-10955 (2013)
Efficient synthesis of protected 3'-deoxyadenosine and 3'-deoxyguanosine from adenosine and guanosine.
Cui Z, et al.
Tetrahedron Letters, 42(4), 561-563 (2001)
A mild conversion of vicinal diols to alkenes. Efficient transformation of ribonucleosides into 2'-ene and 2t', 3'-dideoxynucleosides.
Robins MJ, et al.
Tetrahedron Letters, 25(4), 367-370 (1984)
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