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Merck

336793

Sigma-Aldrich

black, powder, −200 mesh, ≥99% trace metals basis

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About This Item

经验公式(希尔记法):
Ir
CAS号:
分子量:
192.22
EC號碼:
MDL號碼:
分類程式碼代碼:
12352300
PubChem物質ID:
NACRES:
NA.23

化驗

≥99% trace metals basis

形狀

powder

電阻係數

4.71 μΩ-cm

粒徑

−200 mesh

bp

4130 °C (lit.)

mp

2450 °C (lit.)

密度

22.65 g/cm3 (lit.)

SMILES 字串

[Ir]

InChI

1S/Ir

InChI 密鑰

GKOZUEZYRPOHIO-UHFFFAOYSA-N

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象形圖

Flame

訊號詞

Danger

危險聲明

危險分類

Flam. Sol. 1

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

nwg

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Dik-Lung Ma et al.
PloS one, 8(2), e55751-e55751 (2013-03-05)
A cell permeable cyclometalated iridium(III) complex has been developed as a phosphorescent probe for cell imaging. The iridium(III) solvato complex [Ir(phq)2(H2O]2)] preferentially stains the cytoplasm of both live and dead cells with a bright luminescence.
Daniel Shiu-Hin Chan et al.
PloS one, 8(3), e60114-e60114 (2013-03-28)
We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of
Chun-I Lee et al.
Journal of the American Chemical Society, 135(9), 3560-3566 (2013-02-05)
Compounds with carbon-boron bonds are versatile intermediates for building more complex molecules via the elaboration of the carbon-boron bonds into other carbon-element bonds. The synthesis of carbon-boron bonds by catalytic dehydrogenative borylation of carbon-hydrogen bonds with dialkoxyboranes (RO)2BH is particularly
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.

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