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Merck
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文件

306797

Sigma-Aldrich

(S)-(-)-2-氯丙酸

99%

别名:

(S)-(-)-2-Chloropropanoic acid, L-α-氯丙酸

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About This Item

线性分子式:
CH3CH(Cl)CO2H
CAS号:
29617-66-1
分子量:
108.52
Beilstein:
1720257
EC號碼:
411-150-5
MDL號碼:
MFCD00064205
分類程式碼代碼:
12352101
PubChem物質ID:
24858499

化驗

99%

形狀

liquid

光學活性

[α]25/D −14°, neat

折射率

n20/D 1.4347 (lit.)

bp

77 °C/10 mmHg (lit.)

密度

1.249 g/mL at 25 °C (lit.)

SMILES 字串

C[C@H](Cl)C(O)=O

InChI

1S/C3H5ClO2/c1-2(4)3(5)6/h2H,1H3,(H,5,6)/t2-/m0/s1

InChI 密鑰

GAWAYYRQGQZKCR-REOHCLBHSA-N

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應用

(S)-(-)-2-氯丙酸可用于制备(S)-(-)-2-氯丙酰氯 和 DOTMA ([αR*(αR*,α′R*,α”R*,α”′R*)]-(α,α′,α”,α”′)-四甲基-1,4,7,10-四氮杂环十二烷-1,4,7,10-四乙酸)配体。

訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Eye Dam. 1 - Skin Corr. 1A - STOT RE 2

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類（WGK）

WGK 1

閃點（°F）

222.8 °F - closed cup

閃點（°C）

106 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

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A new ytterbium chelate as contrast agent in chemical shift imaging and temperature sensitive probe for MR spectroscopy.
Aime S, et al.
Magnetic Resonance in Medicine : Official Journal of the Society of Magnetic Resonance in Medicine / Society of Magnetic Resonance in Medicine, 35(5), 648-651 (1996)
Synthesis of optically pure. alpha.-alkylated. alpha.-amino acids and a single-step method for enantiomeric excess determination.
Kruizinga WH, et al.
The Journal of Organic Chemistry, 53(8) (1988)
Takashi Nakamura et al.
Journal of computational chemistry, 30(16), 2625-2634 (2009-04-18)
L-2-haloacid dehalogenase (L-DEX) catalyzes the hydrolytic dehalogenation of L-2-haloalkanoic acids to produce the corresponding D-2-hydroxyalkanoic acids. This enzyme is expected to be applicable to the bioremediation of environments contaminated with halogenated organic compounds. We analyzed the reaction mechanism of L-DEX
Gábor Bazsó et al.
The journal of physical chemistry. A, 116(20), 4823-4832 (2012-05-05)
Former assignments of the matrix-isolation infrared (MI-IR) spectrum of 2-chloropropionic acid are revised with the help of near-infrared (NIR) laser irradiation induced change in conformer ratios. This method allows not only the unambiguous assignment of each band in the MI-IR
E A Lock et al.
Toxicology, 123(1-2), 41-51 (1997-11-05)
Administration of a single oral dose of 750 mg/kg L-2-chloropropionic acid (L-CPA) to rats produces marked necrosis to the granule cell layer of the cerebellum by 48 h after dosing. Associated with the neuropathology the rats show locomotor impairment and
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