297801

2-氨基-3,5-二溴苯甲酸甲酯

98%

• 别名: 3,5-二溴邻氨基苯甲酸甲酯
• 线性分子式: Br₂C₆H₂-2-(NH₂)CO₂CH₃
• CAS号: 606-00-8
• 分子量: 308.95
• MDL编号: MFCD00010873
• UNSPSC代码: 12352100
• PubChem化学物质编号: 24857930

属性

• 方案: 98%
• mp: 89-91 °C (lit.)
• SMILES字符串: COC(=O)c1cc(Br)cc(Br)c1N
• InChI: 1S/C8H7Br2NO2/c1-13-8(12)5-2-4(9)3-6(10)7(5)11/h2-3H,11H2,1H3
• InChI key: NGXVMFCGYYHEGC-UHFFFAOYSA-N

说明

一般描述

Methyl 2-amino-3,5-dibromobenzoate participates in cobalt(II) Schiff′s base complex catalyzed oxidation of primary and secondary alcohols to aldehydes and ketones respectively. It also participates in allylic and benzylic oxidation of various cyclic alkenes and benzylic compounds respectively.

应用

Methyl 2-amino-3,5-dibromobenzoate was used in the preparation of ethyl 1-(p-methoxyphenyl)-2-oxocyclopentanecarboxylate via reaction with chloroform containing pyridine.

安全信息

• 象形图: GHS07
• 警示用语：: Warning
• 危险声明: H315,H319,H335
• 预防措施声明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危险分类: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 靶器官: Respiratory system
• 储存分类代码: 11 - Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable
• 个人防护装备: dust mask type N95 (US), Eyeshields, Gloves