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品質等級
化驗
99%
形狀
solid
mp
137-139 °C (lit.)
溶解度
ethanol: soluble 25 mg/mL, clear, colorless
SMILES 字串
O[C@H]([C@H](O)c1ccccc1)c2ccccc2
InChI
1S/C14H14O2/c15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12/h1-10,13-16H/t13-,14+
InChI 密鑰
IHPDTPWNFBQHEB-OKILXGFUSA-N
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一般說明
报道了用手性膦催化剂对 内消旋 氢安息香的去对称化反应 。用芳基磺酰氯和氢氧化钠水溶液处理 内消旋 -对羟基苯甲酸转化为 反式 -二苯乙烯氧化物已有报道 。
應用
内消旋 - 异丙肾上腺素已用于制备反式甲基内消旋 - 苯偶姻的亚磷酸酯。
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 3
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Conversion of meso-Hydrobenzoin with Arylsulfonyl Chlorides and Base to trans-Stilbene Oxide and to 1, 1-Diphenyl-2-(p-toluenesulfonyloxy) ethylene1.
The Journal of Organic Chemistry, 21(11), 1260-1263 (1956)
The Journal of organic chemistry, 69(4), 1389-1392 (2004-02-14)
The desymmetrization of meso-hydrobenzoin is described using chiral phosphine catalysts 8b-d and 9-11. The best enantioselectivity at room temperature was obtained with the newly synthesized phospholane 8c and benzoic anhydride, but the reaction is very slow. Much faster reactions, but
Preparation and crystal structures of trans-methyl meso-hydrobenzoin phosphite and phosphate.
Journal of the American Chemical Society, 96(25), 7790-7797 (1974)
Chromatograms
application for HPLCapplication for HPLC我们的科学家团队拥有各种研究领域经验,包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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