方案
99.9% trace metals basis
表单
wire
电阻率
4.71 μΩ-cm
直径
0.15 mm
沸点
4130 °C (lit.)
mp
2450 °C (lit.)
密度
22.65 g/cm3 (lit.)
SMILES字符串
[Ir]
InChI
1S/Ir
InChI key
GKOZUEZYRPOHIO-UHFFFAOYSA-N
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数量
40mg = 10cm，400mg = 100cm
储存分类代码
13 - Non Combustible Solids
WGK
nwg
闪点(°F)
Not applicable
闪点(°C)
Not applicable
Hana Woo et al.
Journal of the American Chemical Society, 135(12), 4771-4787 (2013-03-06)
Despite the promising photofunctionalities, phosphorescent probes have been examined only to a limited extent, and the molecular features that provide convenient handles for controlling the phosphorescence response have yet to be identified. We synthesized a series of phosphorescence zinc sensors
José Luis Núñez-Rico et al.
Organic letters, 15(8), 2066-2069 (2013-04-12)
Iridium(I) complexes of enantiomerically pure phosphine-phosphite ligands ([Ir(Cl)(cod)(P-OP)]) efficiently catalyze the enantioselective hydrogenation of diverse C═N-containing heterocyclic compounds (benzoxazines, benzoxazinones, benzothiazinones, and quinoxalinones; 25 examples, up to 99% ee). A substrate-to-catalyst ratio as high as 2000:1 was reached.
Yuyang Zhou et al.
Chemical communications (Cambridge, England), 49(31), 3230-3232 (2013-03-14)
Five iridium(III) complexes with two N-heterocyclic carbene (NHC) ligands and an ancillary ligand have been designed and successfully synthesized. With multicolor photoluminescence and low toxicity, these carbene complexes were tested, for the first time, as living cell imaging reagents and
Le Guo et al.
Organic letters, 15(5), 1144-1147 (2013-02-16)
The first α-alkylation of unactivated amides with primary alcohols is described. An effective and robust iridium pincer complex has been developed for selective α-alkylation of tertiary and secondary acetamides involving a "borrowing hydrogen" methodology. The method is compatible with alcohols
Shiguang Pan et al.
Organic letters, 15(8), 1902-1905 (2013-04-02)
A cationic Ir(I) complex-catalyzed O-to-N-alkyl migration in 2-alkoxypyridines bearing a secondary alkyl group on the oxygen atom by C-O bond cleavage is described. The present transformation gave various N-alkylpyridones in moderate to good yields. The addition of sodium acetate played
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