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化驗
98%
折射率
n20/D 1.577 (lit.)
bp
102 °C/15 mmHg (lit.)
225-227 °C (lit.)
mp
16 °C (lit.)
密度
1.16 g/mL at 25 °C (lit.)
SMILES 字串
CSC(SC)SC
InChI
1S/C4H10S3/c1-5-4(6-2)7-3/h4H,1-3H3
InChI 密鑰
YFMZQCCTZUJXEB-UHFFFAOYSA-N
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一般說明
Tris(methylthio)methane is a carboxylic anion equivalent.
應用
Tris(methylthio)methane has been used in synthesis of:
- (−)-nephrosteranic acid and (−)-roccellaric acid
- (4R,5R)-5-({[1-(tert-butyl)-1,1-diphenylsilyl]oxy}methyl)4-[tri(methylthio)methyl]tetrahydro-furan-2-one
- terminal difluoromethylenes
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
186.8 °F - closed cup
閃點(°C)
86 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Organic letters, 13(5), 948-951 (2011-01-28)
An efficient catalytic asymmetric synthesis of chiral γ-butenolides was developed based on the hetero-allylic asymmetric alkylation (h-AAA) in combination with ring closing metathesis (RCM). The synthetic potential of the h-AAA-RCM protocol was illustrated with the facile synthesis of (-)-whiskey lactone
Bioorganic & medicinal chemistry, 11(3), 357-366 (2003-01-09)
Novel nucleoside analogues of both D and L enantiomeric series were prepared by coupling reaction between a 2',3'-dideoxy-3'-modified furanose moiety and four different nucleobases. Though in all cases anomeric mixtures of nucleosides were obtained, the presence of the sterically bulky
From ketones, aldehydes or alkyl halides to terminal 1, 1-difluoroolefins using BrF3.
Journal of Fluorine Chemistry, 126(8), 1239-1245 (2005)
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