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Merck
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文件

252131

Sigma-Aldrich

1,5-二碘戊烷

97%, contains copper as stabilizer

别名:

α,ψ-Diiodopentane, (±)-Hexane-1,2-diol, Pentamethylene diiodide

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About This Item

线性分子式:
I(CH2)5I
CAS号:
628-77-3
分子量:
323.94
EC號碼:
211-054-1
MDL號碼:
MFCD00001101
分類程式碼代碼:
12352100
PubChem物質ID:
24855185
NACRES:
NA.22

化驗

97%

形狀

liquid

包含

copper as stabilizer

折射率

n20/D 1.6002 (lit.)

bp

101-102 °C/3 mmHg (lit.)

密度

2.177 g/mL at 25 °C (lit.)

SMILES 字串

ICCCCCI

InChI

1S/C5H10I2/c6-4-2-1-3-5-7/h1-5H2

InChI 密鑰

IAEOYUUPFYJXHN-UHFFFAOYSA-N

相关类别

一般說明

Electrochemical reduction of 1,5-diiodopentane at carbon electrodes in DMF containing tetramethylammonium perchlorate has been studied by cyclic voltammetry and controlled-potential electrolysis.

應用

1,5-Diiodopentane has been used:
  • as crosslinking reagent, to investigate the cross-linking layer-by-layer films of bioreducible poly(2-dimethylaminoethyl methacrylate) and DNA
  • in preparation of (iodoalkylaminocarbene)tungsten complexes

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

235.4 °F - closed cup

閃點（°C）

113 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Reactions of a-lithio (aminocarbene) tungsten anions with diiodoalkanes: Synthesis of (?-bis (aminocarbene)) ditungsten complexes.
Macomber DW and Madhukar P.
Journal of Organometallic Chemistry, 433(3), 279-285 (1992)
Jenifer Blacklock et al.
The journal of physical chemistry. B, 114(16), 5283-5291 (2010-04-08)
The effect of cross-linking layer-by-layer (LbL) films consisting of bioreducible poly(2-dimethylaminoethyl methacrylate) (rPDMAEMA) and DNA is examined with regard to rigidity, biodegradability, cell adhesion, and transfection activity using 1,5-diiodopentane (DIP) cross-linker. DIP chemically reacts with the tertiary amines of rPDMAEMA
Electrochemical Reduction of 1, 5-Dihalopentanes at Carbon Cathodes in Dimethylformamide.
Pritts WA and Peters DG.
Journal of the Electrochemical Society, 141(12), 3318-3324 (1994)
Ian C Watson et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 25(41), 9678-9690 (2019-05-16)
New N-heterocyclic olefins (NHOs) are described with functionalization on the ligand heterocyclic backbone and terminal alkylidene positions. Various PdII -NHO complexes have been formed and their use as pre-catalysts in Buchwald-Hartwig aminations was explored. The most active system for catalytic

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