所有图片(2)
About This Item
线性分子式:
CH3(CH2)3Li
CAS号:
分子量:
64.06
Beilstein:
1209227
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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形狀
liquid
品質等級
濃度
11.0 M in hexanes
密度
0.761 g/mL at 25 °C
儲存溫度
2-8°C
SMILES 字串
[Li]CCCC
InChI
1S/C4H9.Li/c1-3-4-2;/h1,3-4H2,2H3;
InChI 密鑰
MZRVEZGGRBJDDB-UHFFFAOYSA-N
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一般說明
n-Butyllithium (n-BuLi) is an organolithium reagent commonly used as a strong base to form corresponding lithium salts by the deprotonation of nitrogen, oxygen, phosphorus, and carbon acids. Heterocyclic compounds, such as furans, thiophenes, oxazoles, pyrroles, etc, can be lithiated α to the ring heteroatom using n?BuLi. These lithiated salts reacting in situ with alkyl halides to obtain useful organic compounds by the formation of the C-C bond.
應用
n-BuLi can be used as a reagent for lithium-halogen exchange reactions. Synthesis of various other useful reagents such as lithium diisopropylamide (LDA) and diphenylphosphine is prepared by in situ reaction with n-BuLi . In the polymerization of dienes, it can be employed as an initiator.
包裝
The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.
法律資訊
Sure/Seal is a trademark of Sigma-Aldrich Co. LLC
訊號詞
Danger
危險分類
Aquatic Chronic 2 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 2 - Pyr. Liq. 1 - Repr. 2 - Skin Corr. 1B - STOT RE 1 Inhalation - STOT SE 3 - Water-react 1
標靶器官
Central nervous system, Nervous system
安全危害
儲存類別代碼
4.2 - Pyrophoric and self-heating hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
-7.6 °F - closed cup
閃點（°C）
-22 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
其他客户在看
n-Butyllithium
Ovaska TV, et al.
Encyclopedia of Reagents for Organic Synthesis, Second Edition (2001)
n-Butyllithium.
eEROS (Encyclopedia of Reagents for Organic Synthesis) (2001)
Preparation, Properties, and Safe Handling of Commercial Organolithiums: Alkyllithiums, Lithium sec-Organoamides, and Lithium Alkoxides.
Rathman, Terry `Li? and Schwindeman, James A
Organic Process Research & Development, 18(10), 1192-1210 (2014)
Microstructure-thermal property relationship of high trans-1, 4-poly (butadiene) produced by anionic polymerization of 1, 3-butadiene using an initiator composed of alkyl aluminum, n-butyl lithium, and barium alkoxide
Benvenuta-Tapia JJ, et al.
Polym. Eng. Sci., 49(1), 1-10 (2009)
Diphenylphosphine.
Bianco, VD et al.
Inorganic Syntheses, 16(10), 161-163 (1976)
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