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化驗
≥99.0% (sum of enantiomers, GC)
形狀
solid
光學活性
[α]20/D +10.5±1°, c = 5% in chloroform
bp
273 °C (lit.)
mp
82-86 °C
86-87 °C (lit.)
SMILES 字串
C[C@@H]1CC[C@H]2C(C)(C)[C@H]3C[C@@]12CC[C@@]3(C)O
InChI
1S/C15H26O/c1-10-5-6-11-13(2,3)12-9-15(10,11)8-7-14(12,4)16/h10-12,16H,5-9H2,1-4H3/t10-,11+,12-,14-,15+/m1/s1
InChI 密鑰
SVURIXNDRWRAFU-OGMFBOKVSA-N
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一般說明
(+)-雪松醇是α-雪松烯的结晶水合产物,雪松烯是雪松木油中发现的倍半萜烯。它可以用作化妆品,洗发水和肥皂中的香料成分,也可以用作非化妆品,例如清洁剂和洗涤剂。(±)雪松醇可以通过烷基环戊二烯的分子内Diels-Alder反应合成。
應用
(+)-雪松醇可用作在酸催化剂存在下使用乙酸酐乙酰化制备乙酸雪松酯的起始原料。它也可以作为通过选择性C-H键官能化全合成稀有八角倍半萜(+)-假茴香苷的前体掺入。
儲存類別代碼
11 - Combustible Solids
水污染物質分類(WGK)
WGK 2
閃點(°F)
Not applicable
閃點(°C)
Not applicable
個人防護裝備
Eyeshields, Gloves, type N95 (US)
Journal of the American Chemical Society, 138(51), 16616-16619 (2016-12-15)
Illicium sesquiterpenes have been the subject of numerous synthetic efforts due to their ornate and highly oxidized structures as well as significant biological activities. Herein we report the first chemical synthesis of (+)-pseudoanisatin from the abundant feedstock chemical cedrol (∼$50
Catalytic acetylation of (+)-cedrol with heterogeneous catalyst H2SO4/SiO2 under solvent free conditions
Chemical Intermediates, 1(4), 196-201 (2015)
BMC infectious diseases, 19(1), 800-800 (2019-09-13)
Larviciding is an effective supplementary tool for malaria vector control, but the identification and accessibility of aquatic habitats impedes application. Dissemination of the insect growth regulator, pyriproxyfen (PPF), by gravid Anopheles might constitute a novel application strategy. This study aimed
Autonomic neuroscience : basic & clinical, 168(1-2), 88-92 (2012-02-22)
A previous study reported that when cedrol (odorant) is inhaled directly through the lower airway of the trachea, it decreases the sympathetic nervous activity and blood pressure in totally laryngectomized subjects (Umeno et al., 2008). In the present study, totally
Chirality, 24(2), 147-154 (2011-12-20)
The use of vibrational circular dichroism spectroscopy for the chiral recognition of the two epimers of 6-cedrol, tricyclic sesquiterpenes, which contains oxygen as the heaviest atom, is shown. Bands in the 1500-850 cm(-1) region of the spectra were analyzed to
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