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Merck

22135

Sigma-Aldrich

(+)-雪松醇

≥99.0% (sum of enantiomers, GC)

别名:

(1S,2R,5S,7R,8R)-2,6,6,8-四甲基三环[5.3.1.01.5]十一烷-8-醇

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About This Item

经验公式(希尔记法):
C15H26O
CAS号:
分子量:
222.37
Beilstein:
2206347
EC號碼:
MDL號碼:
分類程式碼代碼:
12352212
PubChem物質ID:
NACRES:
NA.22

化驗

≥99.0% (sum of enantiomers, GC)

形狀

solid

光學活性

[α]20/D +10.5±1°, c = 5% in chloroform

bp

273 °C (lit.)

mp

82-86 °C
86-87 °C (lit.)

SMILES 字串

C[C@@H]1CC[C@H]2C(C)(C)[C@H]3C[C@@]12CC[C@@]3(C)O

InChI

1S/C15H26O/c1-10-5-6-11-13(2,3)12-9-15(10,11)8-7-14(12,4)16/h10-12,16H,5-9H2,1-4H3/t10-,11+,12-,14-,15+/m1/s1

InChI 密鑰

SVURIXNDRWRAFU-OGMFBOKVSA-N

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一般說明

(+)-雪松醇是α-雪松烯的结晶水合产物,雪松烯是雪松木油中发现的倍半萜烯。它可以用作化妆品,洗发水和肥皂中的香料成分,也可以用作非化妆品,例如清洁剂和洗涤剂。(±)雪松醇可以通过烷基环戊二烯的分子内Diels-Alder反应合成。

應用

(+)-雪松醇可用作在酸催化剂存在下使用乙酸酐乙酰化制备乙酸雪松酯的起始原料。它也可以作为通过选择性C-H键官能化全合成稀有八角倍半萜(+)-假茴香苷的前体掺入。

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)


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