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Merck

196274

Sigma-Aldrich

硫代吗啉

98%

别名:

四氢-2H-1,4-噻嗪, 巯基吗啉

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About This Item

经验公式(希尔记法):
C4H9NS
CAS号:
分子量:
103.19
Beilstein:
102550
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

折射率

n20/D 1.538 (lit.)

bp

169 °C (lit.)

溶解度

organic solvents: miscible(lit.)
water: miscible(lit.)

密度

1.026 g/mL at 25 °C (lit.)

SMILES 字串

C1CSCCN1

InChI

1S/C4H9NS/c1-3-6-4-2-5-1/h5H,1-4H2

InChI 密鑰

BRNULMACUQOKMR-UHFFFAOYSA-N

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一般說明

硫代吗啉与 Cu (II)、Pt (II) 和 Ni (II) 盐反应生成复合物,并对其催化活性进行了研究

應用

硫代吗啉已经被用于制备:
  • N-Boc-α-烷基-β-(-氨基)丙氨酸
  • 硫代吗啉- N -硼烷

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

145.4 °F - closed cup

閃點(°C)

63 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Synthesis and comparative reactivity of thiomorpholine-borane: aqueous hydrolysis and oxidation by hypochlorite.
Amezcua CA, et al.
Inorgorganica Chimica Acta, 290(1), 80-85 (1999)
Mesut Kacan et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 118, 572-577 (2013-10-05)
Several Cu(II), Pt(II) and Ni(II) complexes of N-substituted, piperazine (NN donor), morpholine (NO donor) and thiomorpholine (NS donor) derivatives were synthesized and their thermal behavior and catalytic activity in epoxidation reaction of cis-diphenylethylene were studied using oxygen sources NaOCl. The
J I Levin et al.
Bioorganic & medicinal chemistry letters, 16(6), 1605-1609 (2006-01-24)
A series of thiomorpholine sulfonamide hydroxamate TACE inhibitors, all bearing propargylic ether P1' groups, was explored. In particular, compound 5h has excellent in vitro potency against isolated TACE enzyme and in cells, oral activity in a model of TNF-alpha production
Upinder Singh et al.
Bioorganic & medicinal chemistry letters, 13(23), 4209-4212 (2003-11-19)
Combinatorial libraries of N-acylated 5-(S)-aminomethyloxazolidinone derivatives of S-oxide and S,S-dioxide tetrahydro-4(2H)-thiopyranyl and thiomorpholine phenyloxazolidinone series have been synthesized on a solid phase and evaluated for antimicrobial activity. Several novel potent leads have been identified, including orally active oxazolidinones with enhanced
An annulation reaction for the synthesis of morpholines, thiomorpholines, and piperazines from beta-heteroatom amino compounds and vinyl sulfonium salts.
Muhammad Yar et al.
Angewandte Chemie (International ed. in English), 47(20), 3784-3786 (2008-04-12)

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