178969

三仲丁基硼烷 溶液

1.0 M in THF

• 别名: Tris(1-methylpropyl)borane
• 线性分子式: [C₂H₅CH(CH₃)]₃B
• CAS号: 1113-78-6
• 分子量: 182.15
• MDL號碼: MFCD00009325
• 分類程式碼代碼: 12352001
• PubChem物質ID: 24850784
• NACRES: NA.22

属性

• 品質等級: 100
• 反應適用性: reagent type: reductant
• 濃度: 1.0 M in THF
• 密度: 0.799 g/mL at 25 °C
• SMILES 字串: CCC(C)B(C(C)CC)C(C)CC
• InChI: 1S/C12H27B/c1-7-10(4)13(11(5)8-2)12(6)9-3/h10-12H,7-9H2,1-6H3
• InChI 密鑰: YUPAWYWJNZDARM-UHFFFAOYSA-N

说明

應用

Catalyst for:

• Allylic alkylations for synthesis of unsaturated aldehydes and alcohols
• Cis-addition of carbon-hydrogen bonds of pyrroles and thiophenes to alkynes
• Borane-induced radical reduction of alkenyl and alkynyliodanes
• Initiating polymerization for synthesis of polymethylenes and ethylene-propylene
• Asymmetric synthesis of vinylglycidols
• Asymmetric addition of alcohols to vinyl epoxides

安全信息

• 象形圖: GHS02,GHS08,GHS05,GHS07
• 訊號詞: Danger
• 危險聲明: H225,H314,H335,H351
• 防範說明: P210 - P260 - P280 - P305 + P351 + P338 - P370 + P378 - P403 + P235
• 危險分類: Carc. 2 - Flam. Liq. 2 - Skin Corr. 1B - STOT SE 3
• 標靶器官: Respiratory system
• 安全危害: EUH019
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 1
• 閃點（°F）: 1.4 °F
• 閃點（°C）: -17 °C