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Merck

17455

Sigma-Aldrich

α-溴异丁酸叔丁酯

≥98.0%

别名:

2-溴-2-甲基丙酸叔丁酯

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About This Item

线性分子式:
(CH3)2CBrCOOC(CH3)3
CAS号:
分子量:
223.11
Beilstein:
1905654
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

≥98.0%

折射率

n20/D 1.436

密度

1.196 g/mL at 20 °C (lit.)

SMILES 字串

CC(C)(C)OC(=O)C(C)(C)Br

InChI

1S/C8H15BrO2/c1-7(2,3)11-6(10)8(4,5)9/h1-5H3

InChI 密鑰

IGVNJALYNQVQIT-UHFFFAOYSA-N

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應用

tert-Butyl α-bromoisobutyrate was used as an initiator in the atom transfer radical polymerisation (ATRP) of 2-(acetoacetoxy)ethyl methacrylate (AEMA).

象形圖

Exclamation mark

訊號詞

Warning

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Theodora Krasia et al.
Chemical communications (Cambridge, England), (4)(4), 538-539 (2003-03-18)
Reversible addition-fragmentation chain transfer (RAFT) radical polymerisation enables to synthesise well-defined homopolymers and block copolymers based on 2-(acetoacetoxy)ethyl methacrylate, which are capable to strongly coordinate to metals and metal ions.
Shin-Nosuke Nishimura et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 23(60), 15050-15058 (2017-08-11)
Precisely incorporating a wide range of structural and functional multiblocks along a polymer backbone is a significant challenge in polymer chemistry and offers promising opportunities to design highly ordered materials, including controlled polymer folding. Herein, a facile and versatile strategy

实验方案

Polymerization via ATRP procedures demonstrated by Prof. Dave Haddleton's research group at the University of Warwick.

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