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Merck
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文件

162884

Sigma-Aldrich

3,4,7,8-四甲基-1,10-菲罗啉

≥98%

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About This Item

经验公式（希尔记法）:
C16H16N2
CAS号:
1660-93-1
分子量:
236.31
EC號碼:
216-762-4
MDL號碼:
MFCD00004974
分類程式碼代碼:
12352100
PubChem物質ID:
24850010
NACRES:
NA.22

化驗

≥98%

形狀

powder

反應適用性

reagent type: catalyst
reagent type: ligand
reaction type: C-H Activation

mp

277-280 °C (lit.)

溶解度

95% ethanol: soluble 50 mg/mL, clear to hazy, colorless to dark yellow

SMILES 字串

Cc1cnc2c(ccc3c(C)c(C)cnc23)c1C

InChI

1S/C16H16N2/c1-9-7-17-15-13(11(9)3)5-6-14-12(4)10(2)8-18-16(14)15/h5-8H,1-4H3

InChI 密鑰

NPAXPTHCUCUHPT-UHFFFAOYSA-N

一般說明

3,4,7,8-四甲基-1,10-菲咯啉是一种金属螯合剂。作为配体并形成双核 Cu (II) 竹红菌乙素复合物。它还与锌形成四水合物（3,4,7,8-四甲基-1,10-菲咯啉-kappa2 N,N'）锌 (II) 硫代硫酸盐配合物。

應用

以 3,4,7,8-四甲基-1,10-菲咯啉为原料，合成了异相阳离子铱 (III) 配合物，3,4,7,8-四甲基-1,10-菲咯啉-双 [2-（2′,4′-二氟苯基）吡啶] 铱 (III) 六氟磷酸盐。

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

個人防護裝備

Eyeshields, Gloves, type N95 (US)

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Pui-Kei Lee et al.
Dalton transactions (Cambridge, England : 2003), 40(10), 2180-2189 (2010-08-19)
Four new luminescent cyclometallated iridium(III) bis(quinolylbenzaldehyde) diimine complexes [Ir(qba)(2)(N⁁N)](PF(6)) (Hqba = 4-(2-quinolyl)benzaldehyde, N⁁N = 2,2'-bipyridine, bpy (1); 1,10-phenanthroline, phen (2); 3,4,7,8-tetramethyl-1,10-phenanthroline, Me(4)-phen (3); 4,7-diphenyl-1,10-phenanthroline, Ph(2)-phen (4)) have been synthesised and characterised, and their electronic absorption, emission and electrochemical properties investigated.
Yi Sun et al.
Inorganic chemistry, 49(21), 10108-10116 (2010-09-30)
Five new dinuclear Cu(II) complexes were designed and synthesized, using hypocrellin B, a naturally occurring photosensitizer that has received extensive studies as promising photodynamic therapy (PDT) agent, as bridging ligand, and five kinds of diimine ligands, including 2,2'-bipyridine (bpy), 1,10-phenanthroline
M Enriqueta Díaz de Vivar et al.
Acta crystallographica. Section C, Crystal structure communications, 60(Pt 9), m451-m453 (2004-09-04)
In the title complex of zinc(II) with 3,4,7,8-tetramethyl-1,10-phenanthroline (tmph), viz. [Zn(C16H16N2)(H2O)4](S2O3), the metal atom has a monomeric octahedral ZnN2O4 complex environment comprising two N-atom donors from the tmph group and four aqua O-atom donors. The complex cation is connected to
Origin of the large spectral shift in electroluminescence in a blue light emitting cationic iridium (III) complex.
Bolink HJ, et al.
Journal of Materials Chemistry, 17(48), 5032-5041 (2007)
Actions of an inert nickel (II) chelate of tetramethyl-1,10-phenanthroline at calcium-dependent sites on the guinea-pig isolated atrium.
H J Grossman et al.
Methods and findings in experimental and clinical pharmacology, 1(4), 239-260 (1979-10-01)
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