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Merck

160512

Sigma-Aldrich

氯甲酸-9-芴基甲酯

97%, for peptide synthesis

别名:

9-芴甲氧羰酰氯, Fmoc-Cl, 芴甲氧羰酰氯

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About This Item

经验公式(希尔记法):
C15H11ClO2
CAS号:
分子量:
258.70
Beilstein:
2279177
EC號碼:
MDL號碼:
分類程式碼代碼:
12352108
PubChem物質ID:
NACRES:
NA.22

product name

氯甲酸-9-芴基甲酯, 97%

化驗

97%

形狀

solid

mp

62-64 °C (lit.)

應用

peptide synthesis

官能基

Fmoc

儲存溫度

2-8°C

SMILES 字串

ClC(=O)OCC1c2ccccc2-c3ccccc13

InChI

1S/C15H11ClO2/c16-15(17)18-9-14-12-7-3-1-5-10(12)11-6-2-4-8-13(11)14/h1-8,14H,9H2

InChI 密鑰

IRXSLJNXXZKURP-UHFFFAOYSA-N

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應用

在氨基酸 HPLC 分析中,用于衍生化氨基酸;在固相肽合成中用于制备 N-Fmoc 氨基酸。
氨基保护试剂,最近用于合成二环脯氨酸类似物。
用于HPLC分析的氨基酸衍生物。用于多肽和寡核苷酸合成的N端保护试剂。

象形圖

Corrosion

訊號詞

Danger

危險聲明

危險分類

Eye Dam. 1 - Skin Corr. 1B

安全危害

儲存類別代碼

8A - Combustible corrosive hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


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其他客户在看

Helvetica Chimica Acta, 75, 1111-1111 (1992)
Jae Hyun Kim et al.
Nanomaterials (Basel, Switzerland), 11(1) (2020-12-31)
Here, we report a post-synthesis functionalization of the shell of Au nanoclusters (NCs) synthesized using glutathione as a thiolate ligand. The as-synthesized Au NCs are subjected to the post-synthesis functionalization via amidic coupling of dopamine on the cluster shell to
Brett H Pogostin et al.
Molecules (Basel, Switzerland), 24(3) (2019-01-27)
Determining the pKa of key functional groups is critical to understanding the pH-dependent behavior of biological proteins and peptide-based biomaterials. Traditionally, ¹H NMR spectroscopy has been used to determine the pKa of amino acids; however, for larger molecules and aggregating
Journal of the Chemical Society. Chemical Communications, 369-369 (1993)
F Lai et al.
BioTechniques, 14(4), 642-649 (1993-04-01)
Pre-column derivatizations of amino acids often present two major challenges: 1) automation, due to the multi-step manipulations for pH control, reagent addition, mixing and extraction, and 2) effect of matrices in the sample such as salts, buffers and surfactants. Both

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