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Merck
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文件

157422

Sigma-Aldrich

异戊酰氯

98%

别名:

3-甲基丁酰氯

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About This Item

线性分子式:
(CH3)2CHCH2COCl
CAS号:
108-12-3
分子量:
120.58
Beilstein:
741910
EC號碼:
203-552-2
MDL號碼:
MFCD00000738
分類程式碼代碼:
12352100
PubChem物質ID:
24849677
NACRES:
NA.22

化驗

98%

折射率

n20/D 1.416 (lit.)

bp

115-117 °C (lit.)

密度

0.989 g/mL at 25 °C (lit.)

SMILES 字串

CC(C)CC(Cl)=O

InChI

1S/C5H9ClO/c1-4(2)3-5(6)7/h4H,3H2,1-2H3

InChI 密鑰

ISULZYQDGYXDFW-UHFFFAOYSA-N

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相关类别

應用

异戊酰氯被用于合成：
  • furanodictines A和B
  • 四肽酰胺，S-苄基-L-半胱氨酰-L-脯氨酰-L-亮氨酰甘氨酰胺
  • (+)-blastmycinone
  • (R)- 和(S)-2甲基-4-辛醇，某些甘蔗象鼻虫的聚集信息素

訊號詞

Danger

危險聲明

H226,H314,H331

危險分類

Acute Tox. 3 Inhalation - Flam. Liq. 3 - Skin Corr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

87.8 °F - closed cup

閃點（°C）

31 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

分析证书(COA)

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Organoaluminium induced ring-opening of epoxypyranosides. V. Formal total synthesis of antimycin A3 and synthesis of (+)-blastmycinone.
Inghardt T and Frejd T.
Tetrahedron, 47(32), 6483-6492 (1991)
The Synthesis of the Tetrapeptide Amide S-Benzyl-L-cysteinyl-L-prolyl-L-leucylglycinamide
Ressler Cand Vincent du Vigneaud.
Journal of the American Chemical Society, 76(12), 3107-3109 (1954)
Makoto Ogata et al.
Carbohydrate research, 345(2), 230-234 (2009-12-08)
A novel synthesis of furanodictines A [2-acetamido-3,6-anhydro-2-deoxy-5-O-isovaleryl-D-glucofuranose (1)] and B [2-acetamido-3,6-anhydro-2-deoxy-5-O-isovaleryl-D-mannofuranose (2)] is described starting from 2-acetamido-2-deoxy-D-glucose (GlcNAc). The synthetic protocol is based on deriving the epimeric bicyclic 3,6-anhydro sugars [2-acetamido-3,6-anhydro-2-deoxy-D-glucofuranose (4) and 2-acetamido-3,6-anhydro-2-deoxy-D-mannofuranose (5)] from GlcNAc. Reaction with borate
Enantioselective synthesis of (R)-and (S)-2-methyl-4-octanol, the male-produced aggregation pheromone of Curculionidae species.
Baraldi PT, et al.
Tetrahedron Asymmetry, 13(6), 621-624 (2002)
Jessica L Wojtaszek et al.
Cell, 178(1), 152-159 (2019-06-11)
Intrinsic and acquired drug resistance and induction of secondary malignancies limit successful chemotherapy. Because mutagenic translesion synthesis (TLS) contributes to chemoresistance as well as treatment-induced mutations, targeting TLS is an attractive avenue for improving chemotherapeutics. However, development of small molecules with
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